Nearly ferromagnetic metals AFe4Sb12 (A = Ca, Sr, and Ba)

被引:57
作者
Matsuoka, E [1 ]
Hayashi, K
Ikeda, A
Tanaka, K
Takabatake, T
Matsumura, M
机构
[1] Hiroshima Univ, ADSM, Dept Quantum Matter, Higashihiroshima 7398530, Japan
[2] Hiroshima Univ, N BARD, Ctr Mat Sci, Higashihiroshima 7398530, Japan
[3] Kochi Univ, Fac Sci, Kochi 7808520, Japan
关键词
skutterudite compounds; nearly ferromagnetic metals; spin fluctuations;
D O I
10.1143/JPSJ.74.1382
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The magnetic, transport and thermal properties of alkaline-earth-filled skutterudites AFe(4)Sb(12) (A = Ca, Sr, Ba) are reported. All three compounds show maximum magnetic susceptibility and thermopower at 50K and a large electronic specific heat coefficient of 100mJ/molK(2). The electrical resistivity exhibits a shoulder at 70 K and follows quadratic temperature dependence below 9 K. These properties are the characteristics of a nearly ferromagnetic metal. The suppression of ferromagnefic spin fluctuations of the Fe 3d band by applying magnetic fields was manifested as a negative magneto-resistance between 50 and 80K.
引用
收藏
页码:1382 / 1385
页数:4
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