Syntheses and Crystal Structures of Zinc(II) and Nickel(II) Coordination Polymers Based on Diphenic Acid and 1,2-Bis(4-pyridyl)ethane Coligands

被引：4

作者：

Guo, Feng ^{[1
]}

Tian, Lei ^{[2
]}

Li, Bin ^{[2
]}

Zhu, Baoyong ^{[1
]}

Zhang, Xiuling ^{[1
]}

机构：

[1] Dezhou Univ, Dept Chem, Dezhou 253023, Shandong, Peoples R China

[2] Weifang Univ Sci & Technol, Biol Cosmet Inst, Shouguang 262700, Shandong, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2011年 / 21卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Coordination polymers; Crystal structure; Photoluminescence; METAL-ORGANIC FRAMEWORKS; SECONDARY-BUILDING UNITS; PHOTOLUMINESCENCE; DESIGN; COMPLEXES; MOLECULES; CHEMISTRY; SORPTION;

D O I：

10.1007/s10904-010-9435-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two new metal coordination polymers [Zn-2(dpa)(2)(bpa)] (1) and [Ni-4(dpa)(4)(bpa)(3)] (2) [H(2)dpa = 2,4'-biphenyldicarboxylic acid and bpa = 1,2-bis(4-pyridyl)ethane] have been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that complex 1 shows a 2D (4,4) topological net and complex 2 features a 3D network with (4.6(2))(2)(4(2).6(10).8(3)) topology. Fluorescent study of complex 1 shows that it has an emission at 414 nm in the solid state at room temperature.

引用

页码：207 / 211

页数：5

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