Thermolysis of polynuclear platinum(II) acetamidato complexes

被引：2

作者：

Fedotova, T. N. ^{[1
]}

Dobrokhotova, Zh. V. ^{[1
]}

Kuznetsova, G. N. ^{[1
]}

Eremenko, I. L. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S0036023607060149

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermolysis of five polynuclear Pt(II) acetamidato complexes with known structures (I-V) and platinum blue of the composition Pt(NHCOCH3)(2) center dot H2O prepared by two different procedures (VI and VIa) has been studied by differential scanning calorimetry and thermogravimetry. The results of studying the thermolysis of these complexes allows one to assume that the structures of VI and VIa are different: complex VI is polynuclear and consists of binuclear fragments[(H2O)(NHCOCH3)Pt(mu-NHCOCH3)(2)Pt(NHCOCH3)(H2O)], whereas complex VIa is built of fragments [(H2O)(NHCOCH3)Pt(mu-OH)(mu-OH)(mu-NHCOCH3)Pt(NHCOCH3)(2)].

引用

页码：906 / 913

页数：8

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