Syntheses and Crystal Structures of Two Azide-Bridged Dinuclear Zinc(II) Complexes with Schiff Bases and Halides

被引：7
|
作者：
Hui, Rui-Hua [1 ]
Zhou, Peng [1 ]
You, Zhong-Lu [2 ]
机构：
[1] Anshan Normal Univ, Dept Chem, Anshan 114007, Peoples R China
[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 01期
关键词：
azide; crystal structure; Schiff base; synthesis; zinc complex; LIGHT;
D O I：
10.1080/15533174.2011.609503
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two end-on azide-bridged dinuclear Schiff base zinc(II) complexes, [Zn2Br2(mu(1,1)-N-3)L-2(1)]center dot H2O (1) and [Zn2I2(mu(1,1)-N-3)L-2(2)]center dot I (2) (L-1 = 4-bromo-2-[(2-isopropylaminoethylimino)methyl]phenol, L-2 = 2-ethoxy-6-[(2-ethylaminoethylimino)methyl]phenol), have been synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. One Zn atom in (1) is five-coordinated in a square pyramidal geometry, while the other Zn atom in (1) and the Zn atoms in (2) are in tetrahedral geometries.
引用
收藏
页码：135 / 139
页数：5
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