Refractive Index of Liquid D2O for Visible Wavelengths

被引:26
作者
Odhner, Hosanna [1 ]
Jacobs, D. T. [1 ]
机构
[1] Coll Wooster, Dept Phys, Wooster, OH 44691 USA
关键词
HEAVY-WATER;
D O I
10.1021/je200969r
中图分类号
O414.1 [热力学];
学科分类号
摘要
The index of refraction for D2O at common wavelengths was measured for several temperatures at atmospheric pressure. While heavy water's refractive index was precisely measured decades ago using the transition lines of elements, those wavelengths are seldom used now that inexpensive lasers provide a range of available wavelengths. We review those measurements, note some inconsistencies between research groups, and fit the best of the literature data to a simple equation that allows an easy calculation for the refractive index of D2O with an accuracy of +/- 0.0002 at any visible wavelength and between (278 and 359) K. To verify the equation, we then compare the calculated refractive index to our measured values for three He-Ne laser wavelengths (543.5, 594.1, and 632.8) nm over a temperature range from (288 to 338) K and find good agreement.
引用
收藏
页码:166 / 168
页数:3
相关论文
共 15 条
[1]  
[Anonymous], ZH STRUKTURNOY KHIMI
[2]  
AZUAGA NS, 1978, ANALUSIS, V6, P34
[3]  
BENMOUNA M, 1996, LIGHT SCATTERING PRI, P1
[4]   THE REFRACTIVE-INDEX OF COLORLESS LIQUIDS IN THE VISIBLE AND INFRARED - CONTRIBUTIONS FROM THE ABSORPTION OF INFRARED AND ULTRAVIOLET-RADIATION AND THE ELECTRONIC MOLAR POLARIZABILITY BELOW 20500 CM(-1) [J].
BERTIE, JE ;
LAN, Z .
JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (23) :10152-10161
[5]  
Bhatti S. S., 1983, Acoustics Letters, V7, P17
[6]  
Born M., 1999, PRINCIPLES OPTICS, P100
[7]   PIEZO-OPTIC AND ELASTO-OPTIC PROPERTIES OF DEUTERIUM-OXIDE UNDER HIGH-PRESSURE [J].
CHEN, CC ;
VEDAM, K .
JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (02) :1410-1411
[8]   ON THE RELATIVE STABILITIES OF H-BONDED AND D-BONDED WATER DIMERS [J].
ENGDAHL, A ;
NELANDER, B .
JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (04) :1819-1823
[9]   Micellization and Phase Separation for Triblock Copolymer 17R4 in H2O and in D2O [J].
Huff, Alison ;
Patton, Kelly ;
Odhner, Hosanna ;
Jacobs, Donald T. ;
Clover, Bryna C. ;
Greer, Sandra C. .
LANGMUIR, 2011, 27 (05) :1707-1712
[10]   COEXISTENCE CURVE OF A BINARY MIXTURE [J].
JACOBS, DT ;
ANTHONY, DJ ;
MOCKLER, RC ;
OSULLIVAN, WJ .
CHEMICAL PHYSICS, 1977, 20 (02) :219-226