An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction

被引：1577
作者：
Fu, Yanghe [1 ]
Sun, Dengrong [1 ]
Chen, Yongjuan [1 ]
Huang, Renkun [1 ]
Ding, Zhengxin [1 ]
Fu, Xianzhi [1 ]
Li, Zhaohui [1 ]
机构：
[1] Fuzhou Univ, State Key Lab Breeding Base, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, Fuzhou 350002, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 14期
基金：
中国国家自然科学基金;
关键词：
carbon dioxide; metal-organic frameworks; photocatalysis; reduction; CARBON-DIOXIDE; ROOM-TEMPERATURE; WATER; MOFS; BEHAVIOR; ACID;
D O I：
10.1002/anie.201108357
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Let your light shine: The photocatalytic reduction of carbon dioxide to the formate anion under visible light irradiation is for the first time realized over a photoactive Ti-containing metal-organic framework, NH 2-MIL- 125(Ti), which is fabricated by a facile substitution of ligands in the UV-responsive MIL-125(Ti) material (see scheme; TEOA=triethanolamine). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3364 / 3367
页数：4
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