A ferrocene based palladacyclic precatalyst for the Suzuki cross-coupling of aryl chlorides

被引:52
作者
Roca, FX [1 ]
Richards, CJ [1 ]
机构
[1] Univ London Queen Mary Coll, Dept Chem, London E1 4NS, England
关键词
D O I
10.1039/b310526a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Addition of palladium acetate to 2-(dicyclohexylphosphino)phenylferrocene gave palladacycle 16 that is a very effective precatalyst for the Suzuki cross-coupling of aryl chlorides at room temperature (1 mol% 16) or 60 degreesC (greater than or equal to 0.01 mol% 16).
引用
收藏
页码:3002 / 3003
页数:2
相关论文
共 18 条
[1]  
[Anonymous], 1982, COMPREHENSIVE ORGANO
[2]   PREPARATION AND PROPERTIES OF STACKED OLIGOMERIC AND POLYMERIC METALLOCENES [J].
ARNOLD, R ;
MATCHETT, SA ;
ROSENBLUM, M .
ORGANOMETALLICS, 1988, 7 (11) :2261-2266
[3]   Palladacyclic catalysts in C-C and C-heteroatom bond-forming reactions [J].
Bedford, RB .
CHEMICAL COMMUNICATIONS, 2003, (15) :1787-1796
[4]  
Gómez M, 2000, EUR J INORG CHEM, P217
[5]   Macromolecular effect: Synthesis of a ferrocenylmethylphosphine-containing polymer as highly efficient ligands for room-temperature palladium(0)-catalyzed Suzuki cross-coupling reactions of aryl chlorides [J].
Hu, QS ;
Lu, Y ;
Tang, ZY ;
Yu, HB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (10) :2856-2857
[6]   New air-stable planar chiral ferrocenyl monophosphine ligands: Suzuki cross-coupling of aryl chlorides and bromides [J].
Jensen, JF ;
Johannsen, M .
ORGANIC LETTERS, 2003, 5 (17) :3025-3028
[7]   Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C-C, C-N, and C-O bond-forming cross-couplings [J].
Kataoka, N ;
Shelby, Q ;
Stambuli, JP ;
Hartwig, JF .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (16) :5553-5566
[8]   Palladium(II) complexes of 2-dimethylamino-2′-diphenylphosphino-1,1′-binaphthyl (MAP) with unique P,Cσ-coordination and their catalytic activity in allylic substitution, Hartwig-Buchwald amination, and Suzuki coupling [J].
Kocovsky, P ;
Vyskocil, S ;
Císarová, I ;
Sejbal, J ;
Tislerová, I ;
Smrcina, M ;
Lloyd-Jones, GC ;
Stephen, SC ;
Butts, CP ;
Murray, M ;
Langer, V .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (33) :7714-7715
[9]   Recent applications of the Suzuki-Miyaura cross-coupling reaction in organic synthesis [J].
Kotha, S ;
Lahiri, K ;
Kashinath, D .
TETRAHEDRON, 2002, 58 (48) :9633-9695
[10]  
Littke AF, 2002, ANGEW CHEM INT EDIT, V41, P4176, DOI 10.1002/1521-3773(20021115)41:22<4176::AID-ANIE4176>3.0.CO