Origin of the excitonic recombinations in hexagonal boron nitride by spatially resolved cathodoluminescence spectroscopy

被引:92
作者
Jaffrennou, P. [1 ,2 ,3 ]
Barjon, J. [4 ]
Lauret, J. -S. [3 ]
Attal-Tretout, B. [2 ]
Ducastelle, F. [1 ]
Loiseau, A. [1 ]
机构
[1] Off Natl Etud & Rech Aerosp, CNRS, Lab Etude Microstruct, F-92322 Chatillon, France
[2] Chemin Hunier, Off Natl Etud & Rech Aerosp, Dept Mesures Phys, F-91761 Palaiseau, France
[3] Ecole Normale Super, Inst Dalembert, Lab Photon Quant & Mol, F-94235 Cachan, France
[4] Univ Versailles, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France
关键词
D O I
10.1063/1.2821413
中图分类号
O59 [应用物理学];
学科分类号
摘要
The excitonic recombinations in hexagonal boron nitride (hBN) are investigated with spatially resolved cathodoluminescence spectroscopy in the ultraviolet range. Cathodoluminescence images of an individual hBN crystallite reveals that the 215 nm free excitonic line is quite homogeneously emitted along the crystallite, whereas the 220 and 227 nm excitonic emissions are located in specific regions of the crystallite. Transmission electron microscopy images show that these regions contain a high density of crystalline defects. This suggests that the 220 and 227 nm emissions are both produced by the recombination of excitons trapped at structural defects. (C) 2007 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 17 条
[1]   Huge excitonic effects in layered hexagonal boron nitride -: art. no. 026402 [J].
Arnaud, B ;
Lebègue, S ;
Rabiller, P ;
Alouani, M .
PHYSICAL REVIEW LETTERS, 2006, 96 (02)
[2]   Microscopic spatial distribution of bound excitons in high-quality ZnO [J].
Bertram, F ;
Forster, D ;
Christen, J ;
Oleynik, N ;
Dadgar, A ;
Krost, A .
JOURNAL OF CRYSTAL GROWTH, 2004, 272 (1-4) :785-788
[3]   QUASI-PARTICLE BAND-STRUCTURE OF BULK HEXAGONAL BORON-NITRIDE AND RELATED SYSTEMS [J].
BLASE, X ;
RUBIO, A ;
LOUIE, SG ;
COHEN, ML .
PHYSICAL REVIEW B, 1995, 51 (11) :6868-6875
[4]  
Dean P J, 1979, EXCITONS
[5]   NORMAL MODES IN HEXAGONAL BORON NITRIDE [J].
GEICK, R ;
PERRY, CH ;
RUPPRECH.G .
PHYSICAL REVIEW, 1966, 146 (02) :543-&
[6]   Cathodoluminescence imaging and spectroscopy on a single multiwall boron nitride nanotube [J].
Jaffrennou, P. ;
Donatini, F. ;
Barjon, J. ;
Lauret, J.-S. ;
Maguer, A. ;
Attal-Tretout, B. ;
Ducastelle, F. ;
Loiseau, A. .
CHEMICAL PHYSICS LETTERS, 2007, 442 (4-6) :372-375
[7]   Cathodoluminescence image of defects and luminescence centers in ZnS/GaAs(100) [J].
Mitsui, T ;
Yamamoto, N ;
Tadokoro, T ;
Ohta, S .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (12) :6972-6979
[8]   Photoluminescence of hexagonal boron nitride: Effect of surface oxidation under UV-laser irradiation [J].
Museur, Luc ;
Anglos, Demetrios ;
Petitet, Jean-Pierre ;
Michel, Jean-Pierre ;
Kanaev, Andrei V. .
JOURNAL OF LUMINESCENCE, 2007, 127 (02) :595-600
[9]   THEORY OF GRAPHITIC BORON-NITRIDE NANOTUBES [J].
RUBIO, A ;
CORKILL, JL ;
COHEN, ML .
PHYSICAL REVIEW B, 1994, 49 (07) :5081-5084
[10]   Luminescence properties of hexagonal boron nitride: Cathodoluminescence and photoluminescence spectroscopy measurements [J].
Silly, M. G. ;
Jaffrennou, P. ;
Barjon, J. ;
Lauret, J. -S. ;
Ducastelle, F. ;
Loiseau, A. ;
Obraztsova, E. ;
Attal-Tretout, B. ;
Rosencher, E. .
PHYSICAL REVIEW B, 2007, 75 (08)