Characterization of (Ti,Al)N films deposited by off-plane double bend filtered cathodic vacuum arc

被引:2
作者
Cheng, YH
Tay, BK
Lau, SP
Shi, X
Chua, HC
机构
[1] Nanyang Technol Univ, Sch Elect & Elect Engn, Ion Beam Proc Lab, Singapore 639798, Singapore
[2] Image Transform Pte Led, Singapore 118251, Singapore
来源
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS | 2001年 / 19卷 / 02期
关键词
D O I
10.1116/1.1351063
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
(Ti,Al)N films were deposited by a new off-plane double bend filtered cathodic vacuum are technique under a nitrogen atmosphere at room temperature. Scanning electron microscopy and atomic force microscopy were used to observe the surface morphology of the deposited films. X-ray photoelectron spectroscopy was used to determine the composition and bonding structure of the deposited films. A scratch test was used to access the film adhesion. The deposited films are atomically smooth and particle free. The Al/Ti atomic ratio in the deposited films is around 1. The films deposited at the pressure of 1 x 10(-4) Torr are composed of metallic Ti and Al phase and a small amount of (Ti,Al)N phase. For the films deposited at the pressure of 1.5 x 10(-3) Torr, (Ti, AI)N phases are dominant. The scratch test indicates that the critical load increases with increasing deposition pressure up to 1.5 x 10(-3) Torr, then decrease drastically with the further increase of deposition pressure. As substrate bias is increased, critical load increases and reachs the maximum at the bias of 200 V, then decreases at higher bias. The hardness of the deposited films is found to be the main factor that affects the critical load of the thin films. (C) 2001 American Vacuum Society.
引用
收藏
页码:557 / 562
页数:6
相关论文
共 28 条
[1]   LPCVD and PACVD (Ti,Al)N films: morphology and mechanical properties [J].
Anderbouhr, S ;
Ghetta, V ;
Blanquet, E ;
Chabrol, C ;
Schuster, F ;
Bernard, C ;
Madar, R .
SURFACE & COATINGS TECHNOLOGY, 1999, 115 (2-3) :103-110
[2]   A NEW INTERPRETATION OF THE BINDING-ENERGIES IN X-RAY PHOTOELECTRON STUDIES OF OXIDES [J].
BARR, TL ;
SEAL, S ;
CHEN, LM ;
KAO, CC .
THIN SOLID FILMS, 1994, 253 (1-2) :277-284
[3]  
Boxman R. L., 1995, HDB VACUUM ARC SCI T
[4]   Deposition of (Ti, Al)N films by filtered cathodic vacuum arc [J].
Cheng, YH ;
Tay, BK ;
Lau, SP ;
Shi, X ;
Chua, HC .
THIN SOLID FILMS, 2000, 379 (1-2) :76-82
[5]  
CHENG YH, IN PRESS J VAC SCI T
[6]   Comparison of surface oxidation of titanium nitride and chromium nitride films studied by x-ray absorption and photoelectron spectroscopy [J].
Esaka, F ;
Furuya, K ;
Shimada, H ;
Imamura, M ;
Matsubayashi, N ;
Sato, H ;
Nishijima, A ;
Kawana, A ;
Ichimura, H ;
Kikuchi, T .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1997, 15 (05) :2521-2528
[7]   Failure and adhesion characterization of tungsten-carbon single layers, multilayered and graded coatings [J].
Harry, E ;
Rouzaud, A ;
Juliet, P ;
Pauleau, Y ;
Ignat, M .
SURFACE & COATINGS TECHNOLOGY, 1999, 116 :172-175
[8]  
He X.M., 1999, J VAC SCI TECHNOL B, V17, P854
[9]   Bio-compatible low reflective coatings for surgical tools using reactive d.c.-magnetron sputtering and are evaporation - a comparison regarding steam sterilization resistance and nickel diffusion [J].
Hollstein, F ;
Louda, P .
SURFACE & COATINGS TECHNOLOGY, 1999, 120 :672-681
[10]   Oxidation behavior of (Ti1-xAlx)N films prepared by r.f. reactive sputtering [J].
Inoue, S ;
Uchida, H ;
Yoshinaga, Y ;
Koterazawa, K .
THIN SOLID FILMS, 1997, 300 (1-2) :171-176