Sodium borohydride reduction of aldehydes and ketones in the recyclable ionic liquid [BMIM]PF6

被引：20
|
作者：
Howarth, J [1 ]
James, P [1 ]
Ryan, R [1 ]
机构：
[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland
来源：
SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 19期
关键词：
D O I：
10.1081/SCC-100105664
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In our exploration of the new ionic liquid solvents as possible replacements for classical organic solvents, we have found that the reduction of aldehydes and ketones with NaBH4 in the ionic liquid [bmim]PF6 can be achieved. The ionic liquid can be recycled, and in some cases the product alcohol may be distilled directly from the ionic liquid eliminating classical organic solvents entirely.
引用
收藏
页码：2935 / 2938
页数：4
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