Flammability of hydrocarbon and carbon dioxide mixtures

被引:27
作者
Gant, S. E. [1 ]
Pursell, M. R. [1 ]
Lea, C. J. [2 ]
Fletcher, J. [1 ]
Rattigan, W. [1 ]
Thyer, A. M. [3 ]
Connolly, S. [3 ]
机构
[1] Hlth & Safety Lab, Buxton SK17 9JN, England
[2] Lea CFD Associates Ltd, Buxton SK17 6FA, England
[3] Hlth & Safety Execut, Redgrave Court, Bootle L20 7HS, England
关键词
Flammability; Ignition; Hydrocarbon; Carbon dioxide; Jets; Confined explosions; IGNITION; JET;
D O I
10.1016/j.psep.2011.06.017
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The effect of carbon dioxide (CO2) concentration on the ignition behaviour of hydrocarbon and CO2 gas mixtures is examined in both jets and confined explosions. Results from explosion tests are presented using a 201 explosion sphere and an 8 m long section of 1.04 m diameter pipeline. Experiments to assess the flame stability and ignition probability in free-jets are reported for a range of different release velocities. An empirically-based flammability factor model for free-jets is also presented and results are compared to ignition probability measurements previously reported in the literature and those resulting from the present tests. The results help to understand how CO2 changes the severity of fires and explosions resulting from hydrocarbon releases. They also demonstrate that it is possible to ignite gas mixtures when the mean concentration is outside the flammable range. This information may be useful for risk assessments of offshore platforms involved in carbon sequestration or enhanced oil recovery, or in assessing the hazards posed by poorly-inerted hydrocarbon processing plant. Crown Copyright (C) 2011 Published by Elsevier B.V. on behalf of The Institution of Chemical Engineers. All rights reserved.
引用
收藏
页码:472 / 481
页数:10
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