Catalytic Olefin Epoxidation with η5-Cyclopentadienyl Molybdenum Complexes

被引：39

作者：

Grover, Nidhi ^{[1
]}

Kuehn, Fritz E. ^{[1
,2
]}

机构：

[1] Tech Univ Munich, Catalysis Res Ctr, Fac Chem, D-85747 Garching, Germany

[2] Tech Univ Munich, Chair Inorgan Chem, Fac Chem, D-85747 Garching, Germany

来源：

CURRENT ORGANIC CHEMISTRY | 2012年 / 16卷 / 01期

关键词：

Catalysis; cyclopentadiene; epoxidation; homogeneous; molybdenum; olefin; TERT-BUTYL HYDROPEROXIDE; LEWIS-BASE ADDUCTS; DIOXOMOLYBDENUM(VI) COMPLEXES; DIOXO COMPLEXES; TUNGSTEN COMPLEXES; HAPTOTROPIC SHIFTS; RING-SLIPPAGE; ORGANOMETALLIC COMPLEXES; MESOPOROUS MATERIALS; CYCLOALKYL MOIETIES;

D O I：

10.2174/138527212798993103

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Applications of eta(5)-cyclopentadienyl molybdenum complexes as catalysts for achiral and chiral epoxidation of olefins are reviewed. The discussion is categorized according to the different complex types which arise from the variety of ancillary ligands coordinated to the (eta(5)-C5R5)Mo moiety. The yields and turnover frequencies (TOFs) achieved under standard conditions with these different catalysts have been considered and thus, an assessment of the dependence of catalytic activity on the ligand environment is presented.

引用

页码：16 / 32

页数：17

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