Carbon dioxide fixation - Copper(II) and zinc(II) complexes can fix atmospheric carbon dioxide

被引：130
|
作者：
Kong, LY
Zhang, ZH
Zhu, HF
Kawaguchi, H
Okamura, T
Doi, M
Chu, Q
Sun, WY [1 ]
Ueyama, N
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448585, Japan
[3] Osaka Univ, Dept Macromol Sci, Toyonaka, Osaka 560, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 28期
关键词：
carbon dioxide fixation; copper; networks; NMR spectroscopy; zinc;
D O I：
10.1002/anie.200500587
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Carbonato bridges from atmospheric carbon dioxide: The copper(II) and zinc(II) complexes of the novel imidazole-containing polyamine ligand N1-(2-aminoethyl)-N1-(2-imidazolethyl) ethane-1,2-diamine are found to fix carbon dioxide by hydration to μ3-carbonate ligands. This is revealed by IR and solid-state 13C NMR spectroscopic and X-ray crystallographic studies of the two-dimensional complexes (see picture). © 2005 Wiley-VCH Verlag GmbH £ Co. KGaA.
引用
收藏
页码：4352 / 4355
页数：4
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