Strong two-photon absorption of self-assembled butadiyne-linked bisporphyrin

被引：191
作者：
Ogawa, K
Ohashi, A
Kobuke, Y [1 ]
Kamada, K
Ohta, K
机构：
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300101, Japan
[2] Japan Sci & Technol Corp, CREST, Nara 6300101, Japan
[3] Natl Inst Adv Ind Sci & Technol, Photon Res Inst, Ikeda, Osaka 5638577, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 44期
关键词：
D O I：
10.1021/ja035056i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two-photon absorption (2PA) properties of self-assembled porphyrins were investigated. The butadiyne-linked porphyrin array exhibited a 20 times larger 2PA cross section than the meso?meso-linked self-assembled array due to the expansion of π-conjugation. Higher-order nonlinear absorption was also observed in the former porphyrin. Copyright © 2003 American Chemical Society.
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收藏
页码：13356 / 13357
页数：2
相关论文
共 46 条
  • [1] Novel heterocycle-based two-photon absorbing dyes
    Abbotto, A
    Beverina, L
    Bozio, R
    Facchetti, A
    Ferrante, C
    Pagani, GA
    Pedron, D
    Signorini, R
    [J]. ORGANIC LETTERS, 2002, 4 (09) : 1495 - 1498
  • [2] Design of organic molecules with large two-photon absorption cross sections
    Albota, M
    Beljonne, D
    Brédas, JL
    Ehrlich, JE
    Fu, JY
    Heikal, AA
    Hess, SE
    Kogej, T
    Levin, MD
    Marder, SR
    McCord-Maughon, D
    Perry, JW
    Röckel, H
    Rumi, M
    Subramaniam, C
    Webb, WW
    Wu, XL
    Xu, C
    [J]. SCIENCE, 1998, 281 (5383) : 1653 - 1656
  • [3] Building molecular wires from the colours of life: conjugated porphyrin oligomers
    Anderson, HL
    [J]. CHEMICAL COMMUNICATIONS, 1999, (23) : 2323 - 2330
  • [4] CONJUGATED PORPHYRIN LADDERS
    ANDERSON, HL
    [J]. INORGANIC CHEMISTRY, 1994, 33 (05) : 972 - 981
  • [5] Bhawalkar J D, 1997, J Clin Laser Med Surg, V15, P201
  • [6] 3-PHOTON INDUCED UP-CONVERTED FLUORESCENCE FROM AN ORGANIC-COMPOUND - APPLICATION TO OPTICAL POWER LIMITING
    BHAWALKAR, JD
    HE, GS
    PRASAD, PN
    [J]. OPTICS COMMUNICATIONS, 1995, 119 (5-6) : 587 - 590
  • [7] Bonnett Alastair., 2000, ANTIRACISM
  • [8] Two-photon fluorescence imaging of impurity distributions in protein crystals
    Caylor, CL
    Dobrianov, I
    Kimmer, C
    Thorne, RE
    Zipfel, W
    Webb, WW
    [J]. PHYSICAL REVIEW E, 1999, 59 (04): : R3831 - R3834
  • [9] Cooperative enhancement of two-photon absorption in multi-branched structures
    Chung, SJ
    Kim, KS
    Lin, TH
    He, GS
    Swiatkiewicz, J
    Prasad, PN
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (49): : 10741 - 10745
  • [10] Two-photon absorption and excited-state energy-transfer properties of a new multibranched molecule
    Chung, SJ
    Lin, TC
    Kim, KS
    He, GS
    Swiatkiewicz, J
    Prasad, PN
    Baker, GA
    Bright, FV
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (11) : 4071 - 4076
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