Synthesis, molecular structure and characterizations of a novel 2D metal diphosphonate complex

被引：0

作者：

Tong, Yan ^{[1
]}

Ding, De-Gang ^{[1
]}

机构：

[1] Zhengzhou Coll Anim Husb Engn, Dept Human & Basic Sci, Zhengzhou 450011, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2007年 / 37卷 / 08期

关键词：

metal diphosphonate; crystal structure; magnetic properties;

D O I：

10.1080/15533170701606654

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel metal diphosphonate complex [Co-3(H(2)aedp)(2) (Haedp)(2)(H2O)(4)center dot 2H(2)O](n) (1) [H(2)aedp(-) =CH3C(NH3)(PO3H)(2), Haedp(2-) = CH3C(NH3)(PO3)(PO3H)] has been hydrothermally synthesized and structurally characterized. Crystal data: 1, monoclinic, space group C2/c, a = 27.875(6) angstrom, b = 7.1417(14) angstrom, c = 19.913(4) angstrom, beta = 118.43(3)degrees, Z = 4. Complex 1 exhibits a 2-dimensional layer structure with stair-like configuration. Magnetic properties of the compound have been investigated. It shows typical antiferromagnetic behaviors.

引用

页码：591 / 595

页数：5

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