Aspects of allylic alcohol oxidation - a bimetallic heterogeneous selective oxidation catalyst

被引：53

作者：

Lee, AF ^{[1
]}

Gee, JJ ^{[1
]}

Theyers, HJ ^{[1
]}

机构：

[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

来源：

GREEN CHEMISTRY | 2000年 / 2卷 / 06期

关键词：

D O I：

10.1039/b006528p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report the use of a bimetallic Pt,Bi/graphite catalyst for the efficient aerobic selective oxidation of primary allylic alcohols. The influence of the allylic bond location, substrate conformation, and of reaction parameters in modifying aldehyde yield are discussed.

引用

页码：279 / 282

页数：4

共 16 条

[1] Selective oxidation of alcohols and aldehydes on metal catalysts [J].

Besson, M ;

Gallezot, P .

CATALYSIS TODAY, 2000, 57 (1-2) :127-141

[2] PROBING ENSEMBLE EFFECTS IN SURFACE-REACTIONS .1. SITE-SIZE REQUIREMENTS FOR THE DEHYDROGENATION OF CYCLIC HYDROCARBONS ON PT(111) REVEALED BY BISMUTH SITE BLOCKING [J].

CAMPBELL, CT ;

CAMPBELL, JM ;

DALTON, PJ ;

HENN, FC ;

RODRIGUEZ, JA ;

SEIMANIDES, SG .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (02) :806-814

[3] New and ecofriendly options for the production of speciality and fine chemicals [J].

Choudary, BM ;

Kantam, ML ;

Santhi, PL .

CATALYSIS TODAY, 2000, 57 (1-2) :17-32

[4] Environmentally friendly catalytic methods [J].

Clark, JH ;

Macquarrie, DJ .

CHEMICAL SOCIETY REVIEWS, 1996, 25 (05) :303-&

[5] Green Chemistry: challenges and opportunities [J].

Clark, JH .

GREEN CHEMISTRY, 1999, 1 (01) :1-8

[6] Characterization and catalytic activity of palladium dispersed on Kratschmer-Huffman (K-H) soot [J].

Datta, A ;

Khwaja, HI ;

Kelkar, RY ;

Saple, AR ;

Datta, M .

CHEMICAL COMMUNICATIONS, 1996, (07) :851-852

[7] Engineering aspects of the aqueous noble metal catalysed alcohol oxidation [J].

Kluytmans, JHJ ;

Markusse, AP ;

Kuster, BFM ;

Marin, GB ;

Schouten, JC .

CATALYSIS TODAY, 2000, 57 (1-2) :143-155

[8] The origin of SO2 promotion of propane oxidation over Pt/Al2O3 catalysts [J].

Lee, AF ;

Wilson, K ;

Lambert, RM ;

Hubbard, CP ;

Hurley, RG ;

McCabe, RW ;

Gandhi, HS .

JOURNAL OF CATALYSIS, 1999, 184 (02) :491-498

[9]

LEE AM, UNPUB

[10] OXIDATION OF ALCOHOLS WITH MOLECULAR-OXYGEN ON PLATINUM METAL-CATALYSTS IN AQUEOUS-SOLUTIONS [J].

MALLAT, T ;

BAIKER, A .

CATALYSIS TODAY, 1994, 19 (02) :247-283

← 1 2 →