Self-assembly and characterization of grid-type copper(I), silver(I), and zinc(II) complexes

被引:32
作者
Patroniak, V
Stefankiewicz, AR
Lehn, JM
Kubicki, M
机构
[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland
[2] Univ Strasbourg, ISIS, F-67083 Strasbourg, France
关键词
copper; silver; zinc; supramolecular chemistry; self-assembly;
D O I
10.1002/ejic.200500313
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reactions of ligand L, which comprises two bidentate binding units, with copper(I), silver(I), and zinc(II) lead to the self-assembly of the expected supramolecular architectures 1-3, respectively, of the [2 x 2] grid type, containing four ions in tetrahedral coordination sites. The grid-type structures are assigned on the basis of the spectroscopic data in solution, and confirmed in the solid state in the case of complex 2 by X-ray crystallography. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
引用
收藏
页码:4168 / 4173
页数:6
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