Tris(1,4,7,10-tetraoxa-13,16-dithiacyclooctadecane-S,S')ruthenium(II) bis(hexafluorophosphate)-water-methanol (1/2/1)

被引：4

作者：

Blake, AJ ^{[1
]}

Radek, C ^{[1
]}

Schroder, M ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196001497

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title complex, [Ru(C12H24O4S2)(3)](PF6)(2).2H(2)O.CH3OH, the Ru-II ion lies on a crystallographic threefold axis and is coordinated to three symmetry-equivalent macrocyclic ligands via their S donor atoms [Ru-S 2.3620 (9) and 2.3859 (9) Angstrom]. The macrocycle adopts a typical bidentate chelating coordination mode with S donors in exo and O donors in endo orientations.

引用

页码：1401 / 1403

页数：3

共 13 条

[1] Ruthenium complexes of thioether/oxa ionophores: The synthesis and single-crystal X-ray structures of [RuCl2(PPh(3))(2)([15]aneS(2)O(3))], [RuCl(PPh(3))([18]aneS(2)O(4))(2)]PF6, [RuCl(p-MeC(6)H(4)i-Pr)([15]aneS(2)O(3))]PF6, [RuCl(C6H6)([18]aneS(2)O(4))]X (X=PF6 or BPh(4)) and [Ru(C5H5)(PPh(3))([18]aneS(2)O(4))]PF6, ([15]aneS(2)O(3)=1,4,7-trioxa-10,13-dithiacyclopentadecane; [18]aneS(2)O(4)=1,4,7,10-tetraoxa-13,16-dithiacyclooctadecane) [J].

Bell, MN ;

Blake, AJ ;

Gould, RO ;

Parsons, S ;

Radek, C ;

Schroder, M .

TRANSITION METAL CHEMISTRY, 1995, 20 (06) :600-614

[2] THE SYNTHESIS AND SINGLE-CRYSTAL X-RAY STRUCTURE OF THE TETRANUCLEAR SILVER(I) COMPLEX ([AG-2([18]ANES(2)O(4))(2)](2))(PF6)(4) ([18]ANES(2)O(4)=1,4,7,1O-TETRAOXA-13,1 6-DITHIACYCLOOCTADECANE) [J].

BLAKE, AJ ;

GOULD, RO ;

RADEK, C ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (08) :985-986

[3] Synthesis and characterisation of palladium(II) complexes of mixed thioether/oxa ionophores. Crystal structures of [PdCl2([18]aneS(2)O(4))], [Pd([18]aneS(2)O(4))(2)][PF6](2) ([18]aneS(2)O(4)=1,4,7,10-tetraoxa-13,16-dithiacyclooctadecane) and [Pd([18]aneS(3)O(3))(2)][PF6](2) ([18]aneS(3)O(3)=1,4,7-trioxa-10,13,16-trithiacyclooctadecane) [J].

Blake, AJ ;

Gould, RO ;

Radek, C ;

Schroder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (24) :4045-4052

[4] PLATINUM METAL-COMPLEXES OF MIXED THIA OXA IONOPHORES - THE SYNTHESIS AND SINGLE-CRYSTAL X-RAY STRUCTURES OF [PD([15]ANES2O3)2][PF6]2 AND [RUCL(PPH3)([15]ANES2O3)2]PF6.H2O([15]ANES2O3 = 1,4,7-TRIOXA-10,13-DITHIACYCLOPENTADECANE) [J].

BLAKE, AJ ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (12) :3849-3856

[5]

BLAKE AJ, 1995, KACTA CRYST C, V51, P2668

[6] MACROCYCLIC POLYETHER SULFIDE SYNTHESES - PREPARATION OF THIA-CROWN-5, 6 AND 7 COMPOUNDS (1,2) [J].

BRADSHAW, JS ;

HUI, JY ;

CHAN, Y ;

HAYMORE, BL ;

IZATT, RM ;

CHRISTEN.JJ .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1974, 11 (01) :45-49

[7] FASTER DATA-COLLECTION WITHOUT LOSS OF PRECISION - AN EXTENSION OF THE LEARNT PROFILE METHOD [J].

CLEGG, W .

ACTA CRYSTALLOGRAPHICA SECTION A, 1981, 37 (JAN) :22-28

[8] A NITROGEN-GAS-STREAM CRYOSTAT FOR GENERAL X-RAY-DIFFRACTION STUDIES [J].

COSIER, J ;

GLAZER, AM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 (02) :105-107

[9]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[10]

SHELDRICK GM, 1993, SHELXL93 PROGRAM REF

← 1 2 →