Conversion of biomass waste to solid fuel via hydrothermal co-carbonization of distillers grains and sewage sludge

A synergistic process was proposed to prepare hydrochar by hydrothermal co-carbonization (HTcoC) of waste distillers grains with sewage sludge, focusing on hydrochar properties and combustion behavior under different mixing ratios. Results show that the co-hydrochar from HTcoC exhibited excellent synergistic characteristics with relatively high synergistic coefficients (0.1-1.2% for hydrochar yield, 4.8-8.0% for higher heating value (HHV), 8.0-12.6% for organic retention, and 2.2-4.0% for carbon retention, respectively), partially evidenced by FTIR data. And the co-hydrochar showed a higher fuel ratio of 0.09-0.13 with the fixed carbon increased to 8.3-10.0 at an remarkably enhanced coalification degree. Moreover, thermal analysis showed that the co-hydrochar exhibited improved combustion efficiency and a more stable flame. As a result, the HTcoC process with 13.0-22.5% increase in biofuel recovery rate and 25.6-47.7% increase in net energy gain may provide an effective approach for the conversion of both biomass wastes into clean biofuel.