Solvothermal synthesis and magnetic properties of β-Co2P nanorods

被引：3
|
作者：
Li, Tian [1 ]
Liao, Jun Peng [2 ]
Wang, Ying Feng [3 ]
机构：
[1] Yue Yang Vocat Tech Coll, Yueyang 414000, Hunan, Peoples R China
[2] Yue Yang Coll Tradit Chinese Med, Yueyang 414000, Hunan, Peoples R China
[3] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
来源：
MATERIALS SCIENCE-POLAND | 2015年 / 33卷 / 02期
关键词：
solvothermal synthesis; magnetic materials; intermetallic alloys and compounds; nanocrystalline materials; TRANSITION-METAL PHOSPHIDES; ROUTE; FE2P; PRECURSORS; REDUCTION; PNICTIDES; NI2P;
D O I：
10.1515/msp-2015-0049
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Hexagonal high temperature phase beta-Co2P nanorods with a diameter of around 50 nm were synthesized via a mild solvothermal route. The reaction was carried out at 180 degrees C using cobalt chloride hexahydrate (CoCl2 center dot 6H(2)O) as Co source and yellow phosphorous as P source. The composition, structure as well as morphology were characterized by X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS) and transmission electron microscopy (TEM). The magnetic susceptibility curve indicates that the beta-Co2P nanorods show canted antiferromagnetic state, different from the paramagnetic state of orthorhombic low temperature phase beta-Co2P.
引用
收藏
页码：312 / 316
页数：5
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