Solvothermal synthesis and magnetic properties of β-Co2P nanorods

被引：3
|
作者：
Li, Tian [1 ]
Liao, Jun Peng [2 ]
Wang, Ying Feng [3 ]
机构：
[1] Yue Yang Vocat Tech Coll, Yueyang 414000, Hunan, Peoples R China
[2] Yue Yang Coll Tradit Chinese Med, Yueyang 414000, Hunan, Peoples R China
[3] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
来源：
MATERIALS SCIENCE-POLAND | 2015年 / 33卷 / 02期
关键词：
solvothermal synthesis; magnetic materials; intermetallic alloys and compounds; nanocrystalline materials; TRANSITION-METAL PHOSPHIDES; ROUTE; FE2P; PRECURSORS; REDUCTION; PNICTIDES; NI2P;
D O I：
10.1515/msp-2015-0049
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Hexagonal high temperature phase beta-Co2P nanorods with a diameter of around 50 nm were synthesized via a mild solvothermal route. The reaction was carried out at 180 degrees C using cobalt chloride hexahydrate (CoCl2 center dot 6H(2)O) as Co source and yellow phosphorous as P source. The composition, structure as well as morphology were characterized by X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS) and transmission electron microscopy (TEM). The magnetic susceptibility curve indicates that the beta-Co2P nanorods show canted antiferromagnetic state, different from the paramagnetic state of orthorhombic low temperature phase beta-Co2P.
引用
收藏
页码：312 / 316
页数：5
相关论文
共 50 条
  • [1] Solvothermal synthesis and characterization of star-like Co2P microcrystalline
    Liu, Shu-Ling
    Yan, Lu
    Li, Hong-Lin
    Fenmo Yejin Cailiao Kexue yu Gongcheng/Materials Science and Engineering of Powder Metallurgy, 2014, 19 (02): : 307 - 312
  • [2] Solvothermal Synthesis of Flower-Like Co2P Nanostructures and Its Electrochemical Performance
    Liu, Shuling
    Yan, Lu
    Li, Honglin
    SCIENCE OF ADVANCED MATERIALS, 2014, 6 (04) : 746 - 750
  • [3] One-pot solution-phase synthesis of paramagnetic CO2P nanorods
    Hou, HW
    Yang, Q
    Tan, CR
    Ji, GB
    Gu, BX
    Xie, Y
    CHEMISTRY LETTERS, 2004, 33 (10) : 1272 - 1273
  • [4] One-pot solvothermal synthesis of Co2P nanoparticles: An efficient HER and OER electrocatalysts
    Jebaslinhepzybai, Balasingh Thangadurai
    Partheeban, Thamodaran
    Gavali, Deepak S.
    Thapa, Ranjit
    Sasidharan, Manickam
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (42) : 21924 - 21938
  • [5] Co2P nanostructures by thermal decomposition: phase formation and magnetic properties
    Zhang, Nan
    Shan, Aixian
    Wang, Rongming
    Chen, Chinping
    CRYSTENGCOMM, 2012, 14 (04): : 1197 - 1200
  • [6] Solvothermal synthesis and properties of SnO2 nanorods
    Hu, CX
    Wu, YS
    Lü, W
    Shi, YC
    Wei, HY
    Wu, LL
    MATERIALS RESEARCH INNOVATIONS, 2005, 9 (01) : 22 - 23
  • [7] Co2P nanostructures constructed by nanorods: hydrothermal synthesis and applications in the removal of heavy metal ions
    Ni, Yonghong
    Li, Jun
    Jin, Lina
    Xia, Jun
    Hong, Jianming
    Liao, Kaiming
    NEW JOURNAL OF CHEMISTRY, 2009, 33 (10) : 2055 - 2059
  • [8] The reconstructive phase transformation β-CO2P→α-Co2P and the structure of the high-temperature phosphide β-Co2P
    Ellner, M
    Mittemeijer, EJ
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (09): : 2257 - 2260
  • [9] ELECTRONIC-STRUCTURES AND MAGNETIC-PROPERTIES OF FE2P, CO2P AND COMNP
    FUJII, S
    ISHIDA, S
    ASANO, S
    JOURNAL OF PHYSICS F-METAL PHYSICS, 1988, 18 (05): : 971 - 980
  • [10] MAGNETIC AND CRYSTALLOGRAPHIC PROPERTIES OF TERNARY MANGANESE SILICIDES WITH ORDERED CO2P STRUCTURE
    JOHNSON, V
    FREDERIC.CG
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1973, 20 (01): : 331 - 335
12345