A solvothermal synthesis and structure of K2Ag2GeS4 with the simplest helical chains

被引：25

作者：

An, YL ^{[1
]}

Baiyin, MH ^{[1
]}

Liu, X ^{[1
]}

Ji, M ^{[1
]}

Jia, CY ^{[1
]}

Ning, GL ^{[1
]}

机构：

[1] Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 01期

关键词：

solvothermal synthesis; quaternary thiogermanates; chiral chains;

D O I：

10.1016/j.inoche.2003.10.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel helical chain compound K2Ag2GeS4 was synthesized solvothermally. This compound crystallizes in the monoclinic system, space group C2/c, with a = 13.2935(1) Angstrom, b = 6.3590(9) Angstrom, c = 12.4010(2) Angstrom, beta = 122.118(10)degrees, Z = 4. It comprises of the simplest helical chains formed by tetrahedral GeS4 and 2-coordinated bridging Ag+ ions. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：114 / 116

页数：3

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