Polymers with triphenylamine units: Photonic and electroactive materials

被引：192
作者：
Iwan, A. [1 ]
Sek, D. [2 ]
机构：
[1] Inst Elect, Div Electrotechnol & Mat Sci, PL-50369 Wroclaw, Poland
[2] Polish Acad Sci, Ctr Polymer & Carbon Mat, PL-41819 Zabrze, Poland
来源：
PROGRESS IN POLYMER SCIENCE | 2011年 / 36卷 / 10期
关键词：
Triphenylamine; Polymers; Hydrazones; Hydrazides; Poly(azomethine)s; Poly(imide)s; Poly(amine imide)s; Poly(arylate)s; Poly(urethane)s; Poly(ester)s; Hole-transporting materials; Luminescence; Light emitting diodes; Solar cells; LIGHT-EMITTING-DIODES; ELECTROCHROMIC AROMATIC POLYAMIDES; TRI-BRANCHED COPOLYMERS; HOLE TRANSPORT MATERIAL; HIGH-T-G; ELECTROLUMINESCENT PROPERTIES; ELECTROCHEMICAL PROPERTIES; SOLAR-CELLS; SUBSTITUTED POLY(P-PHENYLENEVINYLENE); POLY(AMINE-IMIDE)S BEARING;
D O I：
10.1016/j.progpolymsci.2011.05.001
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Organic hole-transporting materials are intensively investigated as thin-layer electro-optical devices, including organic light-emitting diodes, solar cells, organic field-effect transistors and photo-refractive holographic materials. In this review, we discuss synthetic routes and optical (UV-vis, PL, CV) and electrical (I-V, EL, hole drift mobility) properties of polymers with triphenylamine (TPA) units in the main chain or as pendant groups, such as poly(vinylene)s, poly(amide)s, poly(imide)s, poly(azomethine)s, poly(arylate)s, poly(urethane)s and poly(ester)s. The introduction of vinyl, acetylene, ester, imide, amide or azomethine moieties in TPA leads to new functional materials based on their synergistic effects. The introduction of bulky triphenylamine in macromolecules tends to suppress intermolecular aggregation, reduce the crystallisation propensity and improve the hole-transporting ability of the materials. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1277 / 1325
页数：49
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