Oxidative polymerization of a substituted phenol with ion-paired horseradish peroxidase in an organic solvent

被引：17

作者：

Angerer, PS ^{[1
]}

Studer, A ^{[1
]}

Witholt, B ^{[1
]}

Li, Z ^{[1
]}

机构：

[1] ETH Honggerberg, Inst Biotechnol, CH-8093 Zurich, Switzerland

来源：

MACROMOLECULES | 2005年 / 38卷 / 15期

关键词：

D O I：

10.1021/ma050082h

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A modified procedure for preparation of ion-paired horseradish peroxidase (HRP) in isooctane was presented. The enzymatic system contained less than 0.1% v/v water providing good solubility for hydrophobic phenols. Tert-butyl hyperperoxide was used as the oxidant for HRP-catalyzed polymerization of phenol. The analysis show that the polymerization of 4-hexyloxyphenol with ion-paired HRP in organic solvent resulted in a product mainly containing quinonoid segments.

引用

页码：6248 / 6250

页数：3

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