Quantitative determination of uranium and europium in glass matrix by laser-induced breakdown spectroscopy

被引：48

作者：

Jung, E. C. ^{[1
]}

Lee, D. H. ^{[2
]}

Yun, J. -I. ^{[2
]}

Kim, J. G. ^{[1
]}

Yeon, J. W. ^{[1
]}

Song, K. ^{[1
]}

机构：

[1] Korea Atom Energy Res Inst, Nucl Chem Res Div, Taejon 305600, South Korea

[2] Korea Adv Inst Sci & Technol, Dept Nucl & Quantum Engn, Taejon 305701, South Korea

来源：

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 2011年 / 66卷 / 9-10期

基金：

新加坡国家研究基金会;

关键词：

LIBS; Glass matrix; U; Eu; ONLINE MULTIELEMENT ANALYSIS; EMISSION-SPECTROSCOPY; SPECTROMETRY; PLASMA; ABLATION; SAMPLES; PULSE; MELT;

D O I：

10.1016/j.sab.2011.09.002

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Laser-induced breakdown spectroscopy was applied to the quantitative determination of the elemental composition of glass samples containing U and Eu as a surrogate for highly radioactive glass waste. The emission intensities of both major and minor elements in the samples were measured simultaneously in the wavelength range from 200 to 780 nm by using an echelle spectrometer. Calibration curves for the concentration determination were obtained from the emission intensities at 358.488 nm for U 1, and 459.403 nm for Eu 1. Limits of detection for U and Eu were similar to 150 and similar to 4.2 parts per million, respectively. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：761 / 764

页数：4

共 23 条

[1]

[Anonymous], 2006, Handbook of Laser-Induced Breakdown Spectroscopy

[2] Double pulse laser ablation and plasma: Laser induced breakdown spectroscopy signal enhancement [J].

Babushok, V. I. ;

DeLucia, F. C., Jr. ;

Gottfried, J. L. ;

Munson, C. A. ;

Miziolek, A. W. .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2006, 61 (09) :999-1014

[3] From single pulse to double pulse ns-Laser Induced Breakdown Spectroscopy under water: Elemental analysis of aqueous solutions and submerged solid samples [J].

De Giacomo, A. ;

Dell'Aglio, M. ;

De Pascale, O. ;

Capitelli, M. .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2007, 62 (08) :721-738

[4] Determination of impurities in uranium and plutonium dioxides by laser-induced breakdown spectroscopy [J].

Fichet, P ;

Mauchien, P ;

Moulin, C .

APPLIED SPECTROSCOPY, 1999, 53 (09) :1111-1117

[5] COMPARISON BETWEEN INFRARED AND ULTRAVIOLET-LASER ABLATION AT ATMOSPHERIC-PRESSURE - IMPLICATIONS FOR SOLID SAMPLING INDUCTIVELY-COUPLED PLASMA SPECTROMETRY [J].

GEERTSEN, C ;

BRIAND, A ;

CHARTIER, F ;

LACOUR, JL ;

MAUCHIEN, P ;

SJOSTROM, S ;

MERMET, JM .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1994, 9 (01) :17-22

[6]

Griem H R., 2005, Principles of Plasma Spectroscopy

[7] Preliminary evaluation of laser induced breakdown spectroscopy for slurry samples [J].

Oh, Seong Yong ;

Yueh, Fang Yu ;

Singh, Jagdish P. ;

Herman, Connie C. ;

Zeigler, Kristine .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2009, 64 (01) :113-118

[8] Isotope ratio determination of uranium by optical emission spectroscopy on a laser-produced plasma - basic investigations and analytical results [J].

Pietsch, W ;

Petit, A ;

Briand, A .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1998, 53 (05) :751-761

[9]

Radziemski L.J., 1989, LASER INDUCED PLASMA, V1st

[10] From LASER to LIBS, the path of technology development [J].

Radziemski, LJ .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2002, 57 (07) :1109-1113

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