On stimuli and mechanisms of crystallization

被引:16
作者
Borisov, S. V. [1 ]
Pervukhina, N. V. [1 ]
Magarill, S. A. [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Lavrentiev Av 3, Novosibirsk 630090, Russia
关键词
Crystallization nucleus; Coherent assemblage; Crystallographic analysis; Packing of right-left fragments; Packing of cluster polyanions; Cation and anion sublattices; Sulfide structures; CRYSTAL-STRUCTURE; CRYSTALLOGRAPHIC ANALYSIS; SERIES; HEYROVSKYITE; LILLIANITE; SYMMETRY;
D O I
10.1007/s11224-016-0799-5
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystallographic analysis of a series of compounds with complex composition was carried out from mechanical wave nature of the crystalline state and, as a consequence, a preferential energetic stability of the atomic groups with the local ordering of the atomic positions (point and translational symmetry). Such ordered atomic groups were shown to be nuclei of the crystal structure resulting from the coherent assemblage of the groups. A predominance of monoclinic and orthorhombic crystals in nature is explained by equally probable nuclei formation of right and left atomic configurations as well as the presence of glide plane operations for the mutual packing.
引用
收藏
页码:1673 / 1683
页数:11
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