Selective Oxidation of Benzyl-Alcohol over Biomass-Supported Au/Pd Bioinorganic Catalysts

被引：21

作者：

Deplanche, K. ^{[1
]}

Mikheenko, I. P. ^{[1
]}

Bennett, J. A. ^{[2
]}

Merroun, M. ^{[3
]}

Mounzer, H. ^{[2
]}

Wood, J. ^{[2
]}

Macaskie, L. E. ^{[1
]}

机构：

[1] Univ Birmingham, Sch Biosci, Birmingham B15 2TT, W Midlands, England

[2] Univ Birmingham, Dept Chem Engn, Birmingham B15 2TT, W Midlands, England

[3] Univ Granada, Fac Ciencias, Dept Microbiol, E-18071 Granada, Spain

来源：

TOPICS IN CATALYSIS | 2011年 / 54卷 / 16-18期

基金：

英国生物技术与生命科学研究理事会; 英国工程与自然科学研究理事会;

关键词：

Bioreduction; Core/shell; Escherichia coli; Gold; Palladium; Selective oxidation; SOLVENT-FREE OXIDATION; PALLADIUM CATALYSTS; ESCHERICHIA-COLI; PRECIOUS METALS; PD; AU; HYDROGENATION; GOLD; BIOMANUFACTURE; NANOPARTICLES;

D O I：

10.1007/s11244-011-9691-0

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

We report a novel biochemical method based on the sacrificial hydrogen strategy to synthesise bimetallic Au/Pd nanoparticles supported on bacterial cells. The synergistic effect of Au/Pd over monometallic preparations was demonstrated in the oxidation of benzyl alcohol. The bioinorganic catalysts outperformed a commercial Pd catalyst (5% Pd/C) showing no deactivation and high selectivity towards benzaldehyde.

引用

页码：1110 / 1114

页数：5

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