Techno-economic Assessment for Integrating Biosorption into Rare Earth Recovery Process

被引:48
作者
Jin, Hongyue [1 ]
Park, Dan M. [3 ]
Gupta, Mayank [1 ]
Brewer, Aaron W. [3 ,5 ]
Ho, Lewis [6 ]
Singer, Suzanne L. [4 ]
Bourcier, William L. [3 ]
Woods, Sam [7 ]
Reed, David W. [8 ]
Lammers, Laura N. [9 ]
Sutherland, John W. [2 ]
Jiao, Yongqin [3 ]
机构
[1] Purdue Univ, Sch Ind Engn, Indiana, PA 47907 USA
[2] Purdue Univ, Environm & Ecol Engn, Indiana, PA 47907 USA
[3] Lawrence Livermore Natl Lab, Phys & Life Sci Directorate, Livermore, CA 94550 USA
[4] Lawrence Livermore Natl Lab, Engn Directorate, Livermore, CA 94550 USA
[5] Univ Washington, Earth & Space Sci, Seattle, WA 98195 USA
[6] BioReactor Sci, Lawrenceville, GA 30043 USA
[7] Navajo Transit Energy Co, Farmington, NM 87401 USA
[8] Idaho Natl Lab, Dept Biol & Chem Proc, Idaho Falls, ID 83415 USA
[9] Univ Calif Berkeley, Dept Environm Sci Policy & Management, Berkeley, CA 94720 USA
关键词
Low-grade feedstock; Airlift bioreactor; Mineral recovery; TEA; Mining; LANTHANIDE-BINDING TAGS; COAL BY-PRODUCTS; AQUEOUS-SOLUTIONS; HEAVY-METALS; ELEMENTS; ADSORPTION; MICROORGANISMS; SEPARATION; PEPTIDES; BACTERIA;
D O I
10.1021/acssuschemeng.7b02147
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The current uncertainty in the global supply of rare earth elements (REEs) necessitates the development of novel extraction technologies that utilize a variety of REE source materials. Herein, we examined the techno-economic performance of integrating a biosorption approach into a large-scale process for producing salable total rare earth oxides (TREOs) from various feedstocks. An airlift bioreactor is proposed to carry out a biosorption process mediated by bioengineered rare earth-adsorbing bacteria. Techno-economic assessments were compared for three distinctive categories of REE feedstocks requiring different pre-processing steps. Key parameters identified that affect profitability include REE concentration, composition of the feedstock, and costs of feedstock pretreatment and waste management. Among the 11 specific feedstocks investigated, coal ash from the Appalachian Basin was projected to be the most profitable, largely due to its high-value REE content. Its cost breakdown includes pre-processing (leaching primarily, 77.1%), biosorption (19.4%), and oxalic acid precipitation and TREO roasting (3.5%). Surprisingly, biosorption from the high-grade Bull Hill REE ore is less profitable due to high material cost and low production revenue. Overall, our results confirmed that the application of biosorption to low-grade feedstocks for REE recovery is economically viable.
引用
收藏
页码:10148 / 10155
页数:8
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