Syntheses, Structures, and Magnetic Behavior of New Azide Linked Compounds with One- and Two-Dimensional Structures

被引：4
作者：
Mistry, Subhradeep [1 ]
Sutter, Jean-Pascal [2 ,3 ]
Natarajan, Srinivasan [1 ]
机构：
[1] Indian Inst Sci, Framework Solids Lab, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[2] CNRS, LCC, 205 Route Narbonne, F-31077 Toulouse, France
[3] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 22期
关键词：
Azide; Copper; Nickel; Coordination polymer; Blocking amine; Magnetic properties; ARENE-PERFLUOROARENE INTERACTIONS; COPPER(II) COORDINATION POLYMERS; CU-4 BUILDING CLUSTERS; CRYSTAL-STRUCTURE; POLYNUCLEAR COMPLEXES; NICKEL(II) COMPLEX; LIGANDS; MICELLES; CHAIN; BRIDGE;
D O I：
10.1002/zaac.201700286
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three azide based compounds were synthesized employing aliphatic amines as site blocking agents: [Ni(N-3)(C6H16N2)(2)]ClO4 (I) [C6H16N2 = N,N-diethylethylenediamine (DEDA)], [Cu-8(N-3)(16)(C6H18N4)(2)] (II) [C6H18N4 = tris(2-aminoethyl) amine (TREN)], and [Cu-7(N-3)(14)(C7H19N3)(2)]2H(2)O (III) [C7H19N3 = 3,3-diamino-N-methyldipropylamine (DMDA)]. The compounds I and II have one-dimensional structure and III has a two-dimensional structure. Compound I is a simple linear cationic Ni-azide chain and compound II has Cu-6 azide units forming a column terminated by the copper-metalloligand generated in-situ during the course of the reaction. The charge compensation perchlorate anions occupy spaces in between the chains in I. Compound II packs in a herringbone arrangement, which is not commonly observed in low-dimensional structures. Compound III has one-dimensional copper-azide chains connected through copper-metalloligand forming the two-dimensional structure. All the three compounds exhibit anti-ferromagnetic behavior.
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页码：1730 / 1738
页数：9
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