Tar from biomass/coal-containing briquettes. Evaluation of PAHs

被引:25
作者
Montiano, M. G. [1 ]
Fernandez, A. M. [1 ]
Diaz-Faes, E. [1 ]
Barriocanal, C. [1 ]
机构
[1] CSIC, Inst Nacl Carbon, INCAR, E-33080 Oviedo, Spain
关键词
Sawdust waste; Coal; Briquettes; Tar; PAHs; POLYCYCLIC AROMATIC-HYDROCARBONS; CO-PYROLYSIS; TG-FTIR; WOOD; BLENDS; OILS;
D O I
10.1016/j.fuel.2015.03.067
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The tar derived from the pyrolysis of four briquettes especially prepared for use in cokemaking was studied. The composition of the briquettes included biomass, coal and coal tar as binder. Bio-briquettes can be considered as an alternative ecological fuel and used as a source of energy. Pyrolysis was carried out in order to produce tars. This work studies the effect of adding a sawdust waste on the characteristics of pyrolysis tars. In addition, the tars obtained from bio-briquettes and from biomass-free briquettes were compared. It was found that biomass reduces the amount of sulfur. The aromaticity of bio-tars was found to be lower than that of the tars from the biomass-free briquettes. They therefore contribute less to carcinogenicity, but they have more oxygenated groups. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:261 / 267
页数:7
相关论文
共 36 条
[1]   A review on co-pyrolysis of biomass: An optional technique to obtain a high-grade pyrolysis oil [J].
Abnisa, Faisal ;
Daud, Wan Mohd Ashri Wan .
ENERGY CONVERSION AND MANAGEMENT, 2014, 87 :71-85
[2]   Fuel-oils from co-pyrolysis of scrap tyres with coal and a bituminous waste. Influence of oven configuration [J].
Acevedo, Beatriz ;
Barriocanal, Carmen .
FUEL, 2014, 125 :155-163
[3]   Economic viability of utilizing biomass energy from young stands -: The case of Finland [J].
Ahtikoski, Anssi ;
Heikkila, Jani ;
Alenius, Virpi ;
Siren, Matti .
BIOMASS & BIOENERGY, 2008, 32 (11) :988-996
[4]  
[Anonymous], 2010, IARC Monographs on the Evaluationof Carcinogenic Risks to Humans, V92
[5]   Relationship between coking pressure generated by coal blends and the composition of their primary tars [J].
Barriocanal, C. ;
Diez, M. A. ;
Alvarez, R. ;
Casal, M. D. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2009, 85 (1-2) :514-520
[6]   Characterization of chemical functional groups in macerals across different coal ranks via micro-FTIR spectroscopy [J].
Chen, Yanyan ;
Mastalerz, Maria ;
Schimmelmann, Arndt .
INTERNATIONAL JOURNAL OF COAL GEOLOGY, 2012, 104 :22-33
[7]   Bio-oils from biomass slow pyrolysis: A chemical and toxicological screening [J].
Cordella, Mauro ;
Torri, Cristian ;
Adamiano, Alessio ;
Fabbri, Daniele ;
Barontini, Federica ;
Cozzani, Valerio .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 231 :26-35
[8]   TG-FTIR characterization of coal and biomass single fuels and blends under slow heating rate conditions: Partitioning of the fuel-bound nitrogen [J].
Di Nola, G. ;
de Jong, W. ;
Spliethoff, H. .
FUEL PROCESSING TECHNOLOGY, 2010, 91 (01) :103-115
[9]   Study on the source of polycyclic aromatic hydrocarbons (PAHs) during coal pyrolysis by PY-GC-MS [J].
Dong, Jie ;
Li, Fan ;
Xie, Kechang .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 243 :80-85
[10]   Influence of additives of various origins on thermoplastic properties of coal [J].
Fernandez, A. M. ;
Barriocanal, C. ;
Diez, M. A. ;
Alvarez, R. .
FUEL, 2009, 88 (12) :2365-2372