A Highly Dynamic Covalent Polymer Network without Creep: Mission Impossible?

被引：95

作者：

Van Lijsebetten, Filip ^{[1
,2
]}

Debsharma, Tapas ^{[1
,2
]}

Winne, Johan M. ^{[1
,2
]}

Du Prez, Filip E. ^{[1
,2
]}

机构：

[1] Univ Ghent, Fac Sci, Polymer Chem Res Grp, Ctr Macromol Chem CMaC, Krijgslaan 281-S4, B-9000 Ghent, Belgium

[2] Univ Ghent, Fac Sci, Lab Organ Synth, Dept Organ & Macromol Chem, Krijgslaan 281-S4, B-9000 Ghent, Belgium

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2022年 / 61卷 / 48期

基金：

欧洲研究理事会;

关键词：

Creep Resistance; Dynamic Covalent Networks; Fast Reprocessing; Recyclable Thermoset; Vitrimers; CROSS-LINK DENSITY; ADAPTABLE NETWORKS; INTERNAL CATALYSIS; CHEMICAL-STRUCTURE; PHASE-SEPARATION; VITRIMERS; EXCHANGE; TRANSALKYLATION; VISCOELASTICITY; CHEMISTRY;

D O I：

10.1002/anie.202210405

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dynamic covalent polymer networks provide an interesting solution to the challenging recyclability of thermosets and elastomers. One of the remaining design constraints, however, is balancing thermal reprocessability in the form of material flow with dimensional stability during use. As a result, many chemistries are being investigated in order to improve bond reactivity control and material robustness. This Minireview highlights a number of promising concepts, with a particular emphasis on disconnecting chemical reactivity in low and high temperature regimes to obtain creep resistant, yet highly dynamic polymer networks. In addition, we will highlight the impact of sharp reactivity changes when applying extrapolation-based approaches during rheological analysis. As a result, we are confident that abandoning the myth of "permanent" reactivity will aid in the development of sustainable polymeric materials that can truly combine the benefits of thermoplastic and thermoset behaviour.

引用

页数：14

共 115 条

[1] Using Visible Light to Tune Boronic Acid-Ester Equilibria [J].