Oxidation of secondary aliphatic alcohols by dimethyldioxirane: Kinetics and selectivity

被引：0
|
作者：
Cunningham, MA [1 ]
Vasquez, PC [1 ]
Franklin, PJ [1 ]
Baumstark, AL [1 ]
机构：
[1] Georgia State Univ, Dept Chem, Ctr Biotechnol & Drug Design, Atlanta, GA 30303 USA
来源：
HETEROCYCLIC COMMUNICATIONS | 1998年 / 4卷 / 03期
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D O I：
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The oxidation of acyclic (2-10) and cyclic (11-21) secondary aliphatic alcohols by dimethyldioxirane in acetone at 23 degrees C produced the corresponding ketones in very good to excellent yields. Kinetic data (k(2)'s) were found to be similar for the acyclic series except for the most hindered compounds. The k(2)'s for the cyclic series were found to vary with ring size and to be generally larger than those for the acyclic cases.
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页码：201 / 204
页数：4
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