Synthesis and Solid-State Structure of (4-Hydroxy-3,5-diiodophenyl) phosphine Oxides. Dimeric Motifs with the Assistance of O-H•••O=P Hydrogen Bonds

被引：19

作者：

Bewick, Nicholas A. ^{[1
]}

Arendt, Agata ^{[2
]}

Li, Yan ^{[1
]}

Szafert, Slawomir ^{[2
]}

Lis, Tadeusz ^{[2
]}

Wheeler, Kraig A. ^{[3
]}

Young, Jonathon ^{[1
]}

Dembinski, Roman ^{[1
]}

机构：

[1] Oakland Univ, Dept Chem, Rochester, MI 48309 USA

[2] Univ Wroclaw, Dept Chem, PL-50383 Wroclaw, Poland

[3] Eastern Illinois Univ, Dept Chem, Charleston, IL 61920 USA

来源：

CURRENT ORGANIC CHEMISTRY | 2015年 / 19卷 / 05期

关键词：

Halogen bonding; hydrogen bonding; iodination; phosphine oxides; X-ray crystallography; OXIDATIVE IODINATION; IODINE MONOCHLORIDE; AROMATIC-COMPOUNDS; PEROXIDE; ACID; TRIARYLPHOSPHANES; HALOGENATION; NUCLEOSIDES; DERIVATIVES; COMPLEXES;

D O I：

10.2174/1385272819666141231000247

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(4-Hydroxy-3,5-diiodophenyl)diphenylphosphine oxide, bis(4-hydroxy-3,5-diiodophenyl)(phenyl) phosphine oxide, and tris(4-hydroxy-3,5-diiodophenyl)phosphine oxide were obtained via iodination reactions of corresponding mono-, bis-, and tris(4-hydroxyphenyl)phosphine oxides. Single-crystal X-ray diffraction studies showed each homologue forms O-H center dot center dot center dot O=P and pi-stacking interactions with neighboring molecules to give inversion related dimeric motifs.

引用

收藏

页码：469 / 474

页数：6

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