Selective oxidation of glycerol to formic acid catalyzed by iron salts

被引：54

作者：

Farnetti, E. ^{[1
]}

Crotti, C. ^{[2
]}

机构：

[1] Univ Trieste, Dipartimento Sci Chim & Farmaceut, Via L Giorgieri 1, I-34127 Trieste, Italy

[2] CNR, Ist Struttura Mat, Unita Operat Supporto Trieste, SR 14,Km163-5, I-34149 Trieste, Italy

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 84卷

关键词：

Iron catalysts; Glycerol valorization; Selective oxidation; Hydrogen peroxide; Formic acid; HYDROGEN-PEROXIDE; ALCOHOLS; FUTURE; METAL; DEHYDROGENATION; DECOMPOSITION; CHALLENGES; CONVERSION; COMPLEXES; CHEMISTRY;

D O I：

10.1016/j.catcom.2016.05.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Glycerol is oxidized by hydrogen peroxide to formic acid with excellent selectivity in the presence of iron salts. The oxidation takes place at room temperature in water; at the end of the reaction the catalytic system is still active and available to restart the oxidation. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：1 / 4

页数：4

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