Thymol blue coated glassy carbon electrode for selective determination of titanium

被引:5
作者
El-Maali, NA [1 ]
机构
[1] Assiut Univ, Fac Sci, Dept Chem, Assiut 71516, Egypt
关键词
determination of titanium; modified glassy carbon electrode; anodic stripping voltammetry; application;
D O I
10.1081/AL-100002703
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Highly sensitive and selective coated glassy carbon electrode is described that employs thymol blue (TB), an organic indicator, as modifier. The voltammetric determination of trace amounts of titanium has been studied using this thymol blue coated glassy carbon electrode (TBCGCE). Anodic stripping voltammetry (ASV) was applied to study the various parameters affecting the affinity of titanium ions by the TBCGCE as well as the possible interference by other metal ions. Validation of the proposed method by an independent method, viz. atomic absorption spectroscopy (AAS), has been assessed; therefore, the method has been successfully applied to determine titanium in two standard reference material portland cement samples, then to portland cement and cement clinker. Various Statistical Parameters as well as the quality control chart (X-chart) have been introduced.
引用
收藏
页码:43 / 60
页数:18
相关论文
共 22 条
[1]  
[Anonymous], 1976, ELECTROCHEMICAL STRI
[2]   ELECTROCATALYSIS OF OXYGEN REDUCTION .2. ADSORBED COBALT(III) TETRAPYRIDYLPORPHYRIN ON GLASSY-CARBON ELECTRODE [J].
BETTELHEIM, A ;
CHAN, RJH ;
KUWANA, T .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1979, 99 (03) :391-397
[3]   DIFFERENTIAL-PULSE POLAROGRAPHIC-DETERMINATION OF TRACES OF TITANIUM IN SOLAR GRADE SILICON [J].
BULDINI, PL ;
FERRI, D ;
ZIGNANI, F .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1983, 314 (07) :660-664
[4]  
Campanella L, 1996, ANALUSIS, V24, P35
[5]  
El-Maali NA, 1999, ELECTROANAL, V11, P201, DOI 10.1002/(SICI)1521-4109(199903)11:3<201::AID-ELAN201>3.0.CO
[6]  
2-N
[7]  
El-Maali NA, 1998, ANAL CHIM ACTA, V370, P239
[8]   CHEMICALLY MODIFIED CARBON ELECTRODES [J].
ELLIOTT, CM ;
MURRAY, RW .
ANALYTICAL CHEMISTRY, 1976, 48 (08) :1247-1254
[9]  
ELMAALI N, IN PRESS
[10]   INTRODUCTION OF FUNCTIONAL-GROUPS ONTO CARBON ELECTRODES VIA TREATMENT WITH RADIO-FREQUENCY PLASMAS [J].
EVANS, JF ;
KUWANA, T .
ANALYTICAL CHEMISTRY, 1979, 51 (03) :358-365