Aqueous FeIV=O:: Spectroscopic identification and oxo-group exchange

被引：324
作者：
Pestovsky, O
Stoian, S
Bominaar, EL
Shan, XP
Münck, E
Que, L
Bakac, A
机构：
[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
[3] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA
[4] Iowa State Univ, Ames Lab, Ames, IA 50011 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 42期
关键词：
Fenton reaction; iron; Mossbauer spectroscopy; oxygen; X-ray absorption spectroscopy;
D O I：
10.1002/anie.200502686
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) A combination of techniques (Mössbauer and X-ray absorption spectroscopy, H218O exchange experiments, and DFT calculations) has shown that the reaction of [Fe(H2O) 6]2+ with ozone generates [(H2O) 5FeIV=O]2+ (see calculated structure). The oxidation of selected substrates with [(H2O)5Fe IV=O]2+ yields unique products that are different from those generated in the Fenton reaction or derived from HO• radicals. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：6871 / 6874
页数：4
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