Application of Taguchi approach in describing the mechanical properties and thermal decomposition behavior of poly(vinyl chloride)/clay nanocomposites: Highlighting the Role of organic modifier
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作者:
Esmizadeh, Elnaz
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Iran Polymer & Petrochem Inst, Fac Proc, Tehran, IranIran Polymer & Petrochem Inst, Fac Proc, Tehran, Iran
Esmizadeh, Elnaz
[1
]
Moghri, Mehdi
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Islamic Azad Univ, Kashan Branch, Fac Engn, Dept Polymer Engn, Kashan, IranIran Polymer & Petrochem Inst, Fac Proc, Tehran, Iran
Moghri, Mehdi
[2
]
Saeb, Mohammad Reza
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Inst Color Sci & Technol, Dept Resin & Addit, POB 16765-654, Tehran, IranIran Polymer & Petrochem Inst, Fac Proc, Tehran, Iran
Mechanical and thermal properties of poly(vinyl chloride) (PVC)/nanoclay (NC) composites prepared via melt-blending in a single-screw extruder were investigated. The effects of NC type, NC content, and K-value of PVC were evaluated by using L9 orthogonal array of the Taguchi approach. The most influential variables and significance of interactive effects were examined for the highest values of Young's modulus and hardness. Scanning electron micrographs and X-ray diffraction patterns revealed the formation of exfoliated/intercalated structures. Although the K-value has a minor individual effect on mechanical characteristics, the interaction of the K-value with NC type and NC content is significant. The composites were also characterized and tested by using analysis by thermal gravimetry, differential thermogravimetry, and differential scanning calorimetry methods. The results of the thermal studies indicated that decomposition of the organic modifier of NCs has a catalytic effect on the dehydrochlorination of PVC. This finding justifies the rather low mechanical properties of PVC/organoclay nanocomposites. Fourier-transform infrared spectra of the samples were indicative of accelerated degradation reactions, which provided support for above observations. J. VINYL ADDIT. TECHNOL., 22:182-190, 2016. (c) 2014 Society of Plastics Engineers
机构:
Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
Marquette Univ, Fire Retardant Res Facil, Milwaukee, WI 53201 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Awad, Walid H.
Beyer, Gunter
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Kabelwerk Eupen, B-4700 Eupen, BelgiumPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Beyer, Gunter
Benderly, Daphne
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Elements Special, Hightstown, NJ 08520 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Benderly, Daphne
Ijdo, Wouter L.
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机构:
Elements Special, Hightstown, NJ 08520 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Ijdo, Wouter L.
Songtipya, Ponusa
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机构:
Penn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
Penn State Univ, Dept Plant Pathol, University Pk, PA 16802 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Songtipya, Ponusa
Jimenez-Gasco, Maria del Mar
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h-index: 0
机构:
Penn State Univ, Dept Plant Pathol, University Pk, PA 16802 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Jimenez-Gasco, Maria del Mar
Manias, E.
论文数: 0引用数: 0
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机构:
Penn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Manias, E.
Wilkie, Charles A.
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机构:
Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
Marquette Univ, Fire Retardant Res Facil, Milwaukee, WI 53201 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
机构:
Kyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South KoreaKyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
Azeez, Asif Abdul
Rhee, Kyong Yop
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Kyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South KoreaKyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
Rhee, Kyong Yop
Park, Soo Jin
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Inha Univ, Dept Chem, Inchon 402751, South KoreaKyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
Park, Soo Jin
Hui, David
论文数: 0引用数: 0
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机构:
Kyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
Univ New Orleans, Dept Mech Engn, New Orleans, LA 70148 USAKyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
机构:
Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
Marquette Univ, Fire Retardant Res Facil, Milwaukee, WI 53201 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Awad, Walid H.
Beyer, Gunter
论文数: 0引用数: 0
h-index: 0
机构:
Kabelwerk Eupen, B-4700 Eupen, BelgiumPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Beyer, Gunter
Benderly, Daphne
论文数: 0引用数: 0
h-index: 0
机构:
Elements Special, Hightstown, NJ 08520 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Benderly, Daphne
Ijdo, Wouter L.
论文数: 0引用数: 0
h-index: 0
机构:
Elements Special, Hightstown, NJ 08520 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Ijdo, Wouter L.
Songtipya, Ponusa
论文数: 0引用数: 0
h-index: 0
机构:
Penn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
Penn State Univ, Dept Plant Pathol, University Pk, PA 16802 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Songtipya, Ponusa
Jimenez-Gasco, Maria del Mar
论文数: 0引用数: 0
h-index: 0
机构:
Penn State Univ, Dept Plant Pathol, University Pk, PA 16802 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Jimenez-Gasco, Maria del Mar
Manias, E.
论文数: 0引用数: 0
h-index: 0
机构:
Penn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
Manias, E.
Wilkie, Charles A.
论文数: 0引用数: 0
h-index: 0
机构:
Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
Marquette Univ, Fire Retardant Res Facil, Milwaukee, WI 53201 USAPenn State Univ, Polymer Nanostruct Lab CSPS, University Pk, PA 16802 USA
机构:
Kyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South KoreaKyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
Azeez, Asif Abdul
Rhee, Kyong Yop
论文数: 0引用数: 0
h-index: 0
机构:
Kyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South KoreaKyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
Rhee, Kyong Yop
Park, Soo Jin
论文数: 0引用数: 0
h-index: 0
机构:
Inha Univ, Dept Chem, Inchon 402751, South KoreaKyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
Park, Soo Jin
Hui, David
论文数: 0引用数: 0
h-index: 0
机构:
Kyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea
Univ New Orleans, Dept Mech Engn, New Orleans, LA 70148 USAKyung Hee Univ, Coll Engn, Dept Mech Engn, Yongin 446701, South Korea