Adsorption of ammonium perfluorooctanoate at the air-water interface

被引:0
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作者
Ottewill, GA
Ottewill, RH
机构
[1] Univ Portsmouth, Sch Chem Phys & Radiog, Portsmouth PO1 2DT, Hants, England
[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The adsorption of ammonium perfluorooctanoate has been investigated at the air-water interface as a function of surfactant concentration at various concentrations of ammonium chloride. The area occupied by the surfactant ion was then calculated from the Gibbs equation with allowance for the presence of salt ions. Independently, the area per surfactant ion at the interface was determined by the technique of neutron reflectivity. Within experimental error the two sets of measurements were in good agreement.
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页码:1075 / 1086
页数:12
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