Dilemmas of Dye-Sensitized Solar Cells

被引:65
作者
Bisquert, Juan [1 ]
机构
[1] Univ Jaume 1, Dept Fis, Photovolta & Optoelect Devices Grp, Castellon de La Plana 12071, Spain
关键词
dye-sensitized solar cells; electrochemistry; electrons; nanostructures; photovoltaics; NANOCRYSTALLINE TIO2 FILMS; ELECTRON INJECTION; RUTHENIUM SENSITIZERS; CHARGE-TRANSFER; INTERFACE; MECHANISM; TRANSPORT; VOLTAGE; DESIGN; STATES;
D O I
10.1002/cphc.201100248
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ferrocene to the rescue: The dye-sensitized solar cell allows changes in the energetics of electron transport, molecular absorbers, and hole transport materials to better harvest the energy of solar photons (see picture). A recent paper describing a new dye with a high excited state in combination with ferrocene redox mediator shows progress in this direction. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1633 / 1636
页数:4
相关论文
共 36 条
[1]   Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO2 semiconductor surfaces [J].
Ardo, Shane ;
Meyer, Gerald J. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :115-164
[2]   Lithium-Modulated Conduction Band Edge Shifts and Charge-Transfer Dynamics in Dye-Sensitized Solar Cells Based on a Dicyanamide Ionic Liquid [J].
Bai, Yu ;
Zhang, Jing ;
Wang, Yinghui ;
Zhang, Min ;
Wang, Peng .
LANGMUIR, 2011, 27 (08) :4749-4755
[3]   Energetic factors governing injection, regeneration and recombination in dye solar cells with phthalocyanine sensitizers [J].
Barea, Eva M. ;
Ortiz, Javier ;
Paya, Federico J. ;
Fernandez-Lazaro, Fernando ;
Fabregat-Santiago, Francisco ;
Sastre-Santos, Angela ;
Bisquert, Juan .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (12) :1985-1994
[4]   Quantification of the Effects of Recombination and Injection in the Performance of Dye-Sensitized Solar Cells Based on N-Substituted Carbazole Dyes [J].
Barea, Eva M. ;
Zafer, Ceylan ;
Gultekin, Burak ;
Aydin, Banu ;
Koyuncu, Sermet ;
Icli, Siddik ;
Fabregat Santiago, Francisco ;
Bisquert, Juan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (46) :19840-19848
[5]   Photoinduced ultrafast dye-to-semiconductor electron injection from nonthermalized and thermalized donor states [J].
Benkö, G ;
Kallioinen, J ;
Korppi-Tommola, JEI ;
Yartsev, AP ;
Sundström, V .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (03) :489-493
[6]   Quantification of the effect of 4-tert-butylpyridine addition to I-/I3- redox electrolytes in dye-sensitized nanostructured TiO2 solar cells [J].
Boschloo, Gerrit ;
Haggman, Leif ;
Hagfeldt, Anders .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (26) :13144-13150
[7]   Characteristics of the Iodide/Triiodide Redox Mediator in Dye-Sensitized Solar Cells [J].
Boschloo, Gerrit ;
Hagfeldt, Anders .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1819-1826
[8]   High Open-Circuit Voltage Solid-State Dye-Sensitized Solar Cells with Organic Dye [J].
Chen, Peter ;
Yum, Jun Ho ;
De Angelis, Filippo ;
Mosconi, Edoardo ;
Fantacci, Simona ;
Moon, Soo-Jin ;
Baker, Robin Humphry ;
Ko, Jaejung ;
Nazeeruddin, Md. K. ;
Graetzel, Michael .
NANO LETTERS, 2009, 9 (06) :2487-2492
[9]  
Daeneke T, 2011, NAT CHEM, V3, P211, DOI [10.1038/nchem.966, 10.1038/NCHEM.966]
[10]   Electron Transport and Recombination in Solid-State Dye Solar Cell with Spiro-OMeTAD as Hole Conductor [J].
Fabregat-Santiago, Francisco ;
Bisquert, Juan ;
Cevey, Le ;
Chen, Peter ;
Wang, Mingkui ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :558-562