Phase equilibria of gases and liquids with 1-n-butyl-3-methylimidazolium tetrafluoroborate

被引:0
作者
Anthony, JL [1 ]
Crosthwaite, JM [1 ]
Hert, DG [1 ]
Aki, SNVK [1 ]
Maginn, EJ [1 ]
Brennecke, JF [1 ]
机构
[1] Univ Notre Dame, Dept Chem Engn, Notre Dame, IN 46556 USA
来源
IONIC LIQUIDS AS GREEN SOLVENTS: PROGRESS AND PROSPECTS | 2003年 / 856卷
关键词
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The solubility of carbon dioxide, methane, nitrogen, carbon monoxide and benzene in 1-n-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) at 25 degreesC are reported. In addition, we present densities, which compare very favorably with one set of literature values, for [bmim][BF4]. Accurate values of density are needed in the analysis of gas solubility data. Finally, we report liquid-liquid equilibrium data for [bmim][BF4] with 1-propanol and benzene. Information on vapor-liquid and liquid-liquid equilibrium of gases and liquids with ionic liquids is important for evaluating the use of ionic liquids in a wide variety of processes, including reactions and separations.
引用
收藏
页码:110 / 120
页数:11
相关论文
共 50 条
[21]   On the Use of Ruthenium Dioxide in 1-n-Butyl-3-Methylimidazolium Ionic Liquids as Catalyst Precursor for Hydrogenation Reactions [J].
Liane M. Rossi ;
Giovanna Machado ;
Paulo F. P. Fichtner ;
Sergio R. Teixeira ;
Jairton Dupont .
Catalysis Letters, 2004, 92 :149-155
[22]   Efficient synthesis of cellulose furoates in 1-N-butyl-3-methylimidazolium chloride [J].
Koehler, Sarah ;
Heinze, Thomas .
CELLULOSE, 2007, 14 (05) :489-495
[23]   Surface-enhanced Raman scattering (SERS) of a copper electrode in 1-n-butyl-3-methylimidazolium tetrafluoroborate ionic liquid [J].
Brandao, Christian R. R. ;
Costa, Leonardo A. F. ;
Breyer, Harumi S. ;
Rubim, Joel C. .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (09) :1846-1848
[24]   Efficient synthesis of cellulose furoates in 1-N-butyl-3-methylimidazolium chloride [J].
Sarah Köhler ;
Thomas Heinze .
Cellulose, 2007, 14 :489-495
[25]   Can ionic liquids dissolve wood?: Processing and analysis of lignocellulosic materials with 1-n-butyl-3-methylimidazolium chloride [J].
Fort, Diego A. ;
Remsing, Richard C. ;
Swatloski, Richard P. ;
Moyna, Patrick ;
Moyna, Guillermo ;
Rogers, Robin D. .
GREEN CHEMISTRY, 2007, 9 (01) :63-69
[26]   Preparation of Gold Nanochains in 1-Butyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids [J].
Li Zhongchun ;
Gu Aijun ;
Zhou Quanfa .
RARE METAL MATERIALS AND ENGINEERING, 2009, 38 (08) :1454-1457
[27]   Understanding the large solubility of lidocaine in 1-n-butyl-3-methylimidazolium based ionic liquids using molecular simulation [J].
Ley, Ryan T. ;
Paluch, Andrew S. .
JOURNAL OF CHEMICAL PHYSICS, 2016, 144 (08)
[28]   Two-phase catalytic hydrogenation of olefins by Ru(II) and Co(II) complexes dissolved in 1-n-butyl-3-methylimidazolium tetrafluoroborate ionic liquid [J].
Suarez, PAZ ;
Dullius, JEL ;
Einloft, S ;
deSouza, RF ;
Dupont, J .
INORGANICA CHIMICA ACTA, 1997, 255 (01) :207-209
[29]   1-n-Butyl-3-methylimidazolium ([bmim]) octylsulfate -: an even 'greener' ionic liquid [J].
Wasserscheid, P ;
van Hal, R ;
Bösmann, A .
GREEN CHEMISTRY, 2002, 4 (04) :400-404
[30]   Molecular dynamics study of the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate [J].
Morrow, TI ;
Maginn, EJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (49) :12807-12813