Hybrid, elastomeric hydrogels crosslinked by multifunctional block copolymer micelles

被引：43
作者：
Xiao, Longxi [1 ]
Liu, Chao [1 ]
Zhu, Jiahua [1 ]
Pochan, Darrin J. [1 ]
Jia, Xinqiao [1 ]
机构：
[1] Univ Delaware, Dept Mat Sci & Engn, Delaware Biotechnol Inst, Newark, DE 19716 USA
来源：
SOFT MATTER | 2010年 / 6卷 / 21期
基金：
美国国家卫生研究院; 美国国家科学基金会;
关键词：
POLY(N-BUTYL ACRYLATE)-BLOCK-POLY(ACRYLIC ACID); HIGH MECHANICAL STRENGTH; VOCAL FOLD REGENERATION; HYALURONIC-ACID; DESIGNING MATERIALS; DIBLOCK COPOLYMERS; AQUEOUS-SOLUTIONS; PHASE-BEHAVIOR; NETWORKS; MICELLIZATION;
D O I：
10.1039/c0sm00511h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Amphiphilic block copolymers consisting of hydrophilic, poly(acrylic acid) randomly decorated with acrylate groups and hydrophobic, rubbery poly(n-butyl acrylate) self-assembled into well-defined micelles with an average diameter of similar to 21 nm. Radical polymerization of acrylamide in the presence of the crosslinkable micelles gave rise to hybrid, elastomeric hydrogels whose mechanical properties can be readily tuned by varying the BCM concentration.
引用
收藏
页码：5293 / 5297
页数：5
相关论文
共 50 条
  • [31] Biamphiphilic triblock copolymer micelles as a multifunctional platform for anticancer drug delivery
    Zhu, Wen
    Li, YanLi
    Liu, LiXin
    Zhang, WenLong
    Chen, YongMing
    Xi, Fu
    JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2011, 96A (02) : 330 - 340
  • [32] Micelles and Vesicles Formed by Polyoxometalate-Block Copolymer Composites
    Bu, Weifeng
    Uchida, Sayaka
    Mizuno, Noritaka
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (44) : 8281 - 8284
  • [33] Photocontrollable block copolymer micelles: what can we control?
    Zhao, Yue
    JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (28) : 4887 - 4895
  • [34] Polymeric nanoparticles, micelles and polymersomes from amphiphilic block copolymer
    Cho, Heui Kyoung
    Cheong, In Woo
    Lee, Jung Min
    Kim, Jung Hyun
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2010, 27 (03) : 731 - 740
  • [35] Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
    Le Devedec, Frantz
    Houdaihed, Loujin
    Allen, Christine
    JOVE-JOURNAL OF VISUALIZED EXPERIMENTS, 2016, (116):
  • [36] A Supramolecularly Assisted Transformation of Block-Copolymer Micelles into Nanotubes
    Kim, Sung Ho
    Nederberg, Fredrik
    Jakobs, Robert
    Tan, Jeremy P. K.
    Fukushima, Kazuki
    Nelson, Alshakim
    Meijer, E. W.
    Yang, Yi Yan
    Hedrick, James L.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (25) : 4508 - 4512
  • [37] Morphology Transformation of Hybrid Micelles Self-Assembled from Rod-Coil Block Copolymer and Nanoparticles
    Cai, Chunhua
    Wang, Liquan
    Lin, Jiaping
    Zhang, Xu
    LANGMUIR, 2012, 28 (09) : 4515 - 4524
  • [38] Photo-responsive block copolymer micelles: design and behavior
    Gohy, Jean-Francois
    Zhao, Yue
    CHEMICAL SOCIETY REVIEWS, 2013, 42 (17) : 7117 - 7129
  • [39] Structural changes in block copolymer micelles induced by cosolvent mixtures
    Kelley, Elizabeth G.
    Smart, Thomas P.
    Jackson, Andrew J.
    Sullivan, Millicent O.
    Epps, Thomas H., III
    SOFT MATTER, 2011, 7 (15) : 7094 - 7102
  • [40] Photocleavable amphiphilic diblock copolymer micelles bearing a nitrobenzene block
    Shrivastava, Saurabh
    Matsuoka, Hideki
    COLLOID AND POLYMER SCIENCE, 2016, 294 (05) : 879 - 887
12345