Synthesis and Investigation of the New Derivatives of Poly (Epichlorohydrin) Containing Energetic Groups

被引：8

作者：

Atabaki, Fariborz ^{[1
]}

Keshavarz, Mohammad Hossein ^{[1
]}

Bastam, Naser Noorollahy ^{[1
]}

机构：

[1] Malek Ashtar Univ Technol, Dept Chem, POB 83145-115, Shahin Shahr, Iran

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2018年 / 43卷 / 01期

关键词：

PECH; phenyl hydrazine; 4-nitrophenylhydrazine; 2,4-dinitrophenylhydrazine; energetic poly(epichlorohydrin); CONDENSED-PHASE HEAT; CHEMICAL-MODIFICATION; NUCLEOPHILIC-SUBSTITUTION; SOLID-PROPELLANTS; THIOL COMPOUNDS; COMPUTER CODE; CROSS-LINKING; POLY(EPICHLOROHYDRIN); PREDICTION; EXPLOSIVES;

D O I：

10.1002/prep.201700162

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this research, poly(epichlorohydrin)(PECH) is modified by phenylhydrazine as well as 4-nitro-phenylhydrazine and 2,4-dinitro phenylhydrazine. The chemical structures of the new derivatives of PECH are analyzed by Fourier transform infrared (FT-IR), nuclear magnetic resonance (NMR) and ultraviolet-visible (UV) techniques as well as carbon-hydrogen-nitrogen (CHN) ultimate analysis. Thermal characteristics of reaction products are studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Moreover, glass transition temperature (T-g) of these new polymers are determined. The results indicate that modifications of the poly(epichlorohydrin) are carried out successfully. The new energetic derivatives of PECH are good candidates for chemical industries, which may be considered as a novel class of energetic binders.

引用

页码：83 / 89

页数：7

共 50 条

[1]

Afeefy H. Y., 2011, 69 NIST

[2]

Anoop N., 2013, ENERGETIC POLYM

[3] Chemical Modification of Poly(epichlorohydrin) Using Montmorillonite Clay [J].

Bekkar, Fatima ;

Belbachir, Mohamed .

CHINESE JOURNAL OF CHEMISTRY, 2009, 27 (06) :1174-1178

[4] Synthesis and crosslinking of polyethers that have mesogenic cores and propargyl groups [J].

Bonet, J ;

Callau, L ;

Reina, JA ;

Galià, M ;

Cádiz, V .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (22) :3883-3892

[5] Synthesis and characterization of glycidyl azide polymers using isotactic and chiral poly(epichlorohydrin)s [J].

Brochu, S ;

Ampleman, G .

MACROMOLECULES, 1996, 29 (17) :5539-5545

[6] Synthesis and thermal properties of ferrocene-modified poly(epichlorohydrin-co-2-(methoxymethyl)oxirane) [J].

Cho, Bong-Sang ;

Noh, Si-Tae .

MACROMOLECULAR RESEARCH, 2013, 21 (02) :221-227

[7] Effect of azidation and UV cross-linking of poly(epichlorohydrin) and poly[(ethylene oxide)-ran-(epichlorohydrin)] on gas transport properties [J].

Gacal, Bahadir N. ;

Filiz, Volkan ;

Shishatskiy, Sergey ;

Neumann, Silvio ;

Wind, Jan ;

Abetz, Volker .

JOURNAL OF MEMBRANE SCIENCE, 2014, 467 :126-135

[8] Synthesis of polyether imidazole ionic liquid and its modification on polypropylene crystal structure and mechanical properties [J].

Guo, Liying ;

Ma, Xiuyun ;

Zhang, Bin ;

Wang, Zhiming ;

Huang, Pengcheng .

E-POLYMERS, 2015, 15 (01) :33-37

[9] XPS-ANALYSIS, RAMAN-ANALYSIS, AND IR-ANALYSIS OF A SURFACE PRODUCT FORMED WITHIN ELECTROOXIDATION OF PHENYLHYDRAZINE [J].

HEITBAUM, J .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1977, 105 (5-6) :307-317

[10] Amine functionalized polyethers as bile acid sequestrants: Synthesis and biological evaluation [J].

Huval, CC ;

Bailey, MJ ;

Holmes-Farley, SR ;

Mandeville, WH ;

Miller-Gilmore, K ;

Sacchiero, RJ ;

Dhal, PK .

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2001, 38 (12) :1559-1574

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