Imprinted polymer coated impedimetric nitrate sensor for real-time water quality monitoring

被引:46
作者
Alahi, Md Eshrat E. [1 ]
Mukhopadhyay, Subhas Chandra [1 ]
Burkitt, Lucy [2 ]
机构
[1] Macquarie Univ, Sch Engn, N Ryde, NSW 2109, Australia
[2] Massey Univ, Inst Agr & Environm, Palmerston North, New Zealand
关键词
Ion imprinting polymer; Electrochemical impedance spectroscopy; Nitrate-N; Sensing system; ION-CHROMATOGRAPHIC DETERMINATION; WASTE-WATER; SPECTROPHOTOMETRIC DETERMINATION; INORGANIC ANIONS; DRINKING-WATER; NITRITE; SAMPLES; GROUNDWATER; BIOSENSORS; ELECTRODE;
D O I
10.1016/j.snb.2017.12.104
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The need to determine the nitrate-nitrogen (N) concentration in water with more advanced, inexpensive and accurate sensing systems is pressing. Existing sensing systems are costly, and due to their limitations, they are difficult to use in a continuous real-time monitoring program. Ion-imprinted polymer (IIPs) is a useful technique, which allows the development of low-cost sensors with selective recognition elements. Current research has confirmed that IIPs can be combined into interdigital sensor platforms, for nitrate-N detection in aqueous media. The sensing method is based on electrochemical impedance spectroscopy (EIS) with IIP coating material, and allowing the precise detection of nitrate-N in the range of 1-10 (mg/L). Unknown samples are measured to validate the sensing method. An earlier reported sensing system is used to determine the unknown sample, which is compared with commercial sensors. Results were validated using the standard UV-spectrometric method. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:753 / 761
页数:9
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