Circularly Polarized Lanthanide Luminescence from Langmuir-Blodgett Films Formed from Optically Active and Amphiphilic EuIII-Based Self-Assembly Complexes

被引：88

作者：

Kitchen, Jonathan A. ^{[1
]}

Barry, Dawn E. ^{[1
]}

Mercs, Laszlo ^{[2
]}

Albrecht, Martin ^{[2
]}

Peacock, Robert D. ^{[3
]}

Gunnlaugsson, Thorfinnur ^{[1
]}

机构：

[1] Trinity Coll Dublin, Sch Chem, Ctr Synth & Chem Biol, Coll Green, Dublin 2, Ireland

[2] Univ Coll Dublin, Sch Chem & Chem Biol, Dublin 4, Ireland

[3] Univ Glasgow, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 03期

基金：

欧洲研究理事会; 爱尔兰科学基金会;

关键词：

chirality; Langmuir-Blodgett films; lanthanides; luminescence; surface chemistry; NEAR-INFRARED LUMINESCENCE; ENERGY-TRANSFER; EMISSION PROPERTIES; EUROPIUM COMPLEXES; DIRECTED SYNTHESIS; LIGAND; MONOLAYERS; WATER; FABRICATION; MECHANISM;

D O I：

10.1002/anie.201106863

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Europium union: The development of chiral amphiphilic self-assembled complexes by europium(III)-directed synthesis is described. These systems form stable Langmuir-Blodgett (LB) films on quartz slides to give stable monolayers that exhibit the first example of time-delayed Eu III-centered emission and circularly polarized luminescence (CPL) from an LB film. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：704 / 708

页数：5

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