Oxygen detection using yttria-stabilized zirconia thin films doped with platinum

被引:4
作者
Dimitrov, DT [1 ]
Dushkin, CD [1 ]
机构
[1] Univ Sofia, Fac Chem, Dept Gen & Inorgan Chem, Sofia 1164, Bulgaria
来源
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2005年 / 3卷 / 04期
关键词
yttria stabilized zirconia (YSZ); YSZ thin films; platinum doped YSZ (Pt-YSZ); oxygen detection;
D O I
10.2478/BF02475191
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Yttria stabilized zirconia (YSZ) thin films are obtained using both spray-pyrolysis and dip-coating. The ability of YSZ films incorporated with platinum nanospecies (Pt-YSZ) to detect oxygen is compared with that of pure YSZ thin films using a new experimental setup. With this system, the surface electrical resistance of the films as a function the oxygen content is measured at a fixed temperature. In addition, the effects of thermal annealing on the oxygen sensitivity of the films are observed. Platinum doped samples, Pt-YSZ, show different kinetics of carrier diffusion as compared to pure YSZ samples. (C) Central European Science Journals. All rights reserved.
引用
收藏
页码:605 / 621
页数:17
相关论文
共 15 条
  • [1] BUTURLIN AI, 1983, REV FOREIGN ELECT IN, V10, P3
  • [2] Semiconductor-metal nanocomposites.: Photoinduced fusion and photocatalysis of gold-capped TiO2 (TiO2/Gold) nanoparticles
    Dawson, A
    Kamat, PV
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (05): : 960 - 966
  • [3] DUSHKIN C, UNPUB ANN U SOFIA FA
  • [4] The electrical behaviour of platinum impregnated porous YSZ
    Hendriks, MGHM
    Boukamp, BA
    ten Elshof, JE
    van Zyl, WE
    Verweij, H
    [J]. SOLID STATE IONICS, 2002, 146 (1-2) : 123 - 132
  • [5] Kilner J.A., 2003, MATER TODAY, V6, P30, DOI [10.1016/S1369-7021(03)00332-8, DOI 10.1016/S1369-7021(03)00332-8]
  • [6] Fast oxygen transport in acceptor doped oxides
    Kilner, JA
    [J]. SOLID STATE IONICS, 2000, 129 (1-4) : 13 - 23
  • [7] Kofstad P., 1972, Nonstoichiometry, Diffusion and Electrical Conductivity in Binary Metal Oxides
  • [8] KROOGER FA, 1964, CHEM IMPERFECT CRYST
  • [9] LANDAU LD, 1995, THEORETICAL PHYS 1, V5
  • [10] ORMONT BF, 1973, INTRO CHEM PHYS CRYS