Self-assembled monolayer electrode of a diiron complex with a phenoxo-based dinucleating ligand: observation of molecular oxygen adsorption/desorption in aqueous media

被引：13

作者：

Inomata, Tomohiko ^{[1
]}

Shinozaki, Kazuma ^{[1
]}

Hayashi, Yuya ^{[1
]}

Arii, Hidekazu ^{[2
]}

Funahashi, Yasuhiro ^{[1
]}

Ozawa, Tomohiro ^{[1
]}

Masuda, Hideki ^{[1
]}

机构：

[1] Nagoya Inst Technol, Dept Appl Chem, Showa Ku, Nagoya, Aichi 4668555, Japan

[2] Gakushuin Univ, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 03期

关键词：

D O I：

10.1039/b711802c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The phenoxo-based dinucleating ligand, 2,6-bis[bis(6-pivalamido-2- pyridylmethyl) amino-methyl]-4-aminophenol (1), and its Fe-2(II) complex, [Fe-2(II)(1)(PhCOO)(2)](CF3SO3) (2), were prepared and 2 deposited on the Au surface (2/Au) is much more stable than in solution and exhibits redox behavior in aqueous media as well as reversible adsorption/desorption of oxygen at room temperature.

引用

页码：392 / 394

页数：3

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