Organic-Inorganic Hybrid Saponites Obtained by Intercalation of Titano-Silsesquioxane

被引：11
|
作者：
Carniato, Fabio [1 ,2 ]
Bisio, Chiara [1 ,2 ,3 ]
Gatti, Giorgio [1 ,2 ]
Guidotti, Matteo [3 ]
Sordelli, Laura [3 ]
Marchese, Leonardo [1 ,2 ]
机构：
[1] Univ Piemonte Orientale, Dipartimento Sci & Tecnol Avanzate, I-15121 Alessandria, Italy
[2] Univ Piemonte Orientale, Nano SISTEMI Interdisciplinary Ctr, I-15121 Alessandria, Italy
[3] CNR, ISTM, Milan, Italy
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 03期
关键词：
clays; organic-inorganic hybrids; saponites; silsesquioxanes; titanium; METAL FUNCTIONALIZED POSS; EFFECTIVE CORE POTENTIALS; HETEROGENEOUS CATALYSTS; MOLECULAR CALCULATIONS; EPOXIDATION CATALYST; NANOCOMPOSITES; AMMONIUM; ROUTE; GELS;
D O I：
10.1002/asia.201000664
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterization of two bifunctional composite materials based on synthetic saponite clays is here presented. These materials were prepared by intercalation of a Ti-containing aminopropylisobutyl polyhedral oligomeric silsesquioxane (Ti-NH2POSS) in synthetic saponite samples containing interlayer sodium (NaSAP) or protons (H-SAP). Hybrid organic-inorganic materials, Ti-NHM-1 and Ti-NHM-2, were obtained upon ion exchange. Structural, spectroscopic, and thermal properties of both hybrid materials were investigated in detail along with their catalytic activity in cyclohexene oxidation.
引用
收藏
页码：914 / 921
页数：8
相关论文
共 50 条
  • [21] Preparation and characterization of organic-inorganic hybrid composites based on multiepoxy silsesquioxane and cyanate resin
    Lu, Tingli
    Liang, Guozheng
    Guo, Zhian
    Journal of Applied Polymer Science, 2006, 101 (06): : 3652 - 3658
  • [22] Organic-Inorganic Hybrid Compounds Containing Polyhedral Oligomeric Silsesquioxane for Conservation of Stone Heritage
    Son, Seunghwan
    Won, Jongok
    Kim, Jeong-Jin
    Jang, Yun Deuk
    Kang, Yong Soo
    Kim, Sa Dug
    ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (02) : 393 - 401
  • [23] Adsorption of hazardous and noxious 4-nitrophenol by a silsesquioxane organic-inorganic hybrid material
    Marília Reginato de Barros
    Otávio Rôvere Bittencourt
    Paola Zimmermann Crocomo
    Gabriela Mafra
    Eduardo Carasek
    Hérica Aparecida Magosso
    Cristiane Luisa Jost
    João Paulo Winiarski
    Journal of Sol-Gel Science and Technology, 2021, 99 : 402 - 412
  • [24] Hybrid organic-inorganic thermoplastics: Styryl-based polyhedral oligomeric silsesquioxane polymers
    Haddad, TS
    Lichtenhan, JD
    MACROMOLECULES, 1996, 29 (22) : 7302 - 7304
  • [25] Organic-inorganic luminescent composites obtained by the intercalation of organic dyes into the layered rare-earth hydroxides
    Gu, Qingyang
    Wu, Yifei
    Yu, Sainan
    INORGANICA CHIMICA ACTA, 2019, 487 : 162 - 168
  • [26] Preparation of organic-inorganic nanohybrids by intercalation reactions
    Fujita, K
    Tagaya, H
    Kadokawa, J
    KOBUNSHI RONBUNSHU, 2000, 57 (04) : 214 - 219
  • [27] Lightweight hybrid organic-inorganic geopolymers obtained using polyurethane waste
    Bergamonti, L.
    Taurino, R.
    Cattani, L.
    Ferretti, D.
    Bondioli, F.
    CONSTRUCTION AND BUILDING MATERIALS, 2018, 185 : 285 - 292
  • [28] Organic-inorganic nanocomposites of polystyrene with polyhedral oligomeric silsesquioxane
    Kim, Kyung-Min
    POLYMER-KOREA, 2006, 30 (05) : 380 - 384
  • [29] Organic-Inorganic Hybrid Materials
    Garcia-Martinez, Jesus-Maria
    Collar, Emilia P.
    POLYMERS, 2021, 13 (01) : 1 - 4
  • [30] Hybrid organic-inorganic sensors
    Bescher, E
    Mackenzie, JD
    MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 1998, 6 (2-3): : 145 - 154
12345