Organic-Inorganic Hybrid Saponites Obtained by Intercalation of Titano-Silsesquioxane

被引：11
|
作者：
Carniato, Fabio [1 ,2 ]
Bisio, Chiara [1 ,2 ,3 ]
Gatti, Giorgio [1 ,2 ]
Guidotti, Matteo [3 ]
Sordelli, Laura [3 ]
Marchese, Leonardo [1 ,2 ]
机构：
[1] Univ Piemonte Orientale, Dipartimento Sci & Tecnol Avanzate, I-15121 Alessandria, Italy
[2] Univ Piemonte Orientale, Nano SISTEMI Interdisciplinary Ctr, I-15121 Alessandria, Italy
[3] CNR, ISTM, Milan, Italy
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 03期
关键词：
clays; organic-inorganic hybrids; saponites; silsesquioxanes; titanium; METAL FUNCTIONALIZED POSS; EFFECTIVE CORE POTENTIALS; HETEROGENEOUS CATALYSTS; MOLECULAR CALCULATIONS; EPOXIDATION CATALYST; NANOCOMPOSITES; AMMONIUM; ROUTE; GELS;
D O I：
10.1002/asia.201000664
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterization of two bifunctional composite materials based on synthetic saponite clays is here presented. These materials were prepared by intercalation of a Ti-containing aminopropylisobutyl polyhedral oligomeric silsesquioxane (Ti-NH2POSS) in synthetic saponite samples containing interlayer sodium (NaSAP) or protons (H-SAP). Hybrid organic-inorganic materials, Ti-NHM-1 and Ti-NHM-2, were obtained upon ion exchange. Structural, spectroscopic, and thermal properties of both hybrid materials were investigated in detail along with their catalytic activity in cyclohexene oxidation.
引用
收藏
页码：914 / 921
页数：8
相关论文
共 50 条
  • [1] Intercalation Route to New Hybrid Organic-Inorganic Superconductors
    Choy, Jin-Ho
    Kwon, Soon-Jae
    Hwang, Seong-Ju
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1998, 311 : 383 - 388
  • [2] Intercalation route to new hybrid organic-inorganic superconductors
    Choy, Jin-Ho
    Kwon, Soon-Jae
    Hwang, Seong-Ju
    Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 1998, 311 : 383 - 388
  • [3] Intercalation Route to New Hybrid Organic-Inorganic Superconductors
    Choy, Jin-Ho
    Kwon, Soon-Jae
    Hwang, Seong-Ju
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1998, 310 : 205 - 210
  • [4] Intercalation route to new hybrid organic-inorganic superconductors
    Choy, Jin-Ho
    Kwon, Soon-Jae
    Hwang, Seong-Ju
    Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 1998, 310 : 205 - 210
  • [5] Deposition of organic-inorganic hybrid polymer thin films with a silsesquioxane unit
    Ogawa, Yamato
    Mayuzumi, Satsuki
    Miyayama, Takumi
    Usui, Hiroaki
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2022, 61 (SE)
  • [6] Organic-inorganic hybrid poly(silsesquioxane) monoliths with controlled macro- and mesopores
    Nakanishi, K
    Kanamori, K
    JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (35-36) : 3776 - 3786
  • [7] In-vitro imaging with biodegradable hybrid organic-inorganic bridged silsesquioxane nanoparticles
    Fatieiev, Yevhen
    Croissant, Jonas
    Julfakyan, Khachatur
    Deng, Lin
    Anjum, Dalaver
    Gurinov, Andrei
    Khashab, Niveen
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [8] Organic-inorganic hybrid materials based on various polyhedral oligomeric silsesquioxane (POSS)
    Fronoiu, Oana M.
    Constantin, Floriana
    Garea, Sorina A.
    Negru, Georgiana
    Iovu, Horia
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
  • [9] Hybrid organic-inorganic POSS (polyhedral oligomeric silsesquioxane)/polypropylene nanocomposite filaments
    B. S. Butola
    Mangala Joshi
    Sachin Kumar
    Fibers and Polymers, 2010, 11 : 1137 - 1145
  • [10] Hybrid Organic-Inorganic POSS (Polyhedral Oligomeric silsesquioxane)/Polypropylene Nanocomposite Filaments
    Butola, B. S.
    Joshi, Mangala
    Kumar, Sachin
    FIBERS AND POLYMERS, 2010, 11 (08) : 1137 - 1145
12345