Production of Liquid Biofuels from Microalgae Chlorella sp. via Catalytic Slow Pyrolysis

被引:16
作者
Sardi, Bambang [1 ]
Ningrum, Rifa Fatwa [1 ]
Ardiansyah, Vicky Aziz [1 ]
Qadariyah, Lailatul [1 ]
Mahfud, Mahfud [1 ]
机构
[1] Inst Teknol Sepuluh Nopember, Dept Chem Engn, Surabaya 60111, Indonesia
关键词
Activated carbon; Chlorella sp; HZSM-5; Liquid biofuel; Slow catalytic pyrolysis; BIO-OIL PRODUCTION; CO-PYROLYSIS; BIOMASS; RESIDUES; QUALITY; WASTE; FUEL;
D O I
10.14716/ijtech.v13i1.4358
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study investigates the effects of catalyst preparation techniques on the yield and quality of liquid biofuel produced from slow catalytic pyrolysis of microalgae Chlorella sp. using various catalysts, including acid catalysts (HZSM-5) and base catalysts (activated carbon). The effects of different temperatures, catalyst loading, and reaction time on the yield and quality of liquid biofuels, including chemical composition, density, and the resulting viscosity at the optimal variable, were investigated. The results showed that slow catalytic pyrolysis using 1 wt.% activated carbon catalyst, a temperature of 550 degrees C, and a reaction time of three hours produced a maximum yield of liquid biofuel at 50.38 wt.% with high aromatic hydrocarbons, less oxygen and acid, a density of 0.88 kg/L, and a viscosity of 5.79 cSt that satisfied specifications of biodiesel No. 2. Slow catalytic pyrolysis with a variety of catalyst types and catalyst preparation techniques affects the increase in yield and quality adjustment of liquid biofuel. The proposed technology can be further developed for commercial applications, replacing conventional diesel fuel.
引用
收藏
页码:147 / 156
页数:10
相关论文
共 26 条
[1]   Technologies and developments of third generation biofuel production [J].
Alaswad, A. ;
Dassisti, M. ;
Prescott, T. ;
Olabi, A. G. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2015, 51 :1446-1460
[2]  
Amin A., 2016, Egyptian Journal of Petroleum, V25, P509, DOI 10.1016/j.ejpe.2015.11.002
[3]   Ceria promoted deoxygenation and denitrogenation of Thalassiosira weissflogii and its model compounds by catalytic in-situ pyrolysis [J].
Aysu, Tevfik ;
Maroto-Valer, M. Mercedes ;
Sanna, Aimaro .
BIORESOURCE TECHNOLOGY, 2016, 208 :140-148
[4]   Photobioreactor cultivation and catalytic pyrolysis of the microalga Desmodesmus communis (Chlorophyceae) for hydrocarbons production by HZSM-5 zeolite cracking [J].
Conti, Roberto ;
Pezzolesi, Laura ;
Pistocchi, Rossella ;
Torri, Cristian ;
Massoli, Patrizio ;
Fabbri, Daniele .
BIORESOURCE TECHNOLOGY, 2016, 222 :148-155
[5]   Microwave-assisted fast co-pyrolysis behaviors and products between microalgae and polyvinyl chloride [J].
Dai, Minquan ;
Xu, Hao ;
Yu, Zhaosheng ;
Fang, Shiwen ;
Chen, Lin ;
Gu, Wenlu ;
Ma, Xiaoqian .
APPLIED THERMAL ENGINEERING, 2018, 136 :9-15
[6]   Microwave-assisted pyrolysis of microalgae for biofuel production [J].
Du, Zhenyi ;
Li, Yecong ;
Wang, Xiaoquan ;
Wan, Yiqin ;
Chen, Qin ;
Wang, Chenguang ;
Lin, Xiangyang ;
Liu, Yuhuan ;
Chen, Paul ;
Ruan, Roger .
BIORESOURCE TECHNOLOGY, 2011, 102 (07) :4890-4896
[7]   Non-catalytic hydropyrolysis of microalgae to produce liquid biofuels [J].
Duan, Peigao ;
Bai, Xiujun ;
Xu, Yuping ;
Zhang, Aiyun ;
Wang, Feng ;
Zhang, Lei ;
Miao, Juan .
BIORESOURCE TECHNOLOGY, 2013, 136 :626-634
[8]   Forecasting of CO2 emissions in Iran based on time series and regression analysis [J].
Hosseini, Seyed Mohsen ;
Saifoddin, Amirali ;
Shirmohammadi, Reza ;
Aslani, Alireza .
ENERGY REPORTS, 2019, 5 :619-631
[9]   The catalytic pyrolysis of microalgae to produce syngas [J].
Hu, Zhifeng ;
Ma, Xiaoqian ;
Li, Longjun ;
Wu, Jie .
ENERGY CONVERSION AND MANAGEMENT, 2014, 85 :545-550
[10]   Bio-oil production through pyrolysis of blue-green algae blooms (BGAB): Product distribution and bio-oil characterization [J].
Hu, Zhiquan ;
Zheng, Yang ;
Yan, Feng ;
Xiao, Bo ;
Liu, Shiming .
ENERGY, 2013, 52 :119-125