A coumarin-fused 'off-on' fluorescent probe for highly selective detection of hydrazine

被引：40

作者：

Wang, Mei ^{[1
]}

Wang, Xiaoli ^{[1
]}

Li, Xueyan ^{[1
,2
]}

Yang, Ziqi ^{[1
]}

Guo, Zhenbo ^{[1
,2
]}

Zhang, Jiangyan ^{[1
,3
]}

Ma, Jingjun ^{[4
]}

Wei, Chao ^{[1
,2
,3
]}

机构：

[1] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China

[2] Hebei Univ, Key Lab Chem Biol Hebei Prov, Baoding 071002, Peoples R China

[3] Hebei Univ, Minist Educ, Key Lab Med Chem & Mol Diag, Baoding 071002, Peoples R China

[4] Hebei Agr Univ, Coll Sci & Technol, Huanghua 061100, Peoples R China

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2020年 / 230卷

基金：

中国国家自然科学基金;

关键词：

Hydrazine; Highly selective; Large off-on response; Fluorescent probe; Cellular imaging; NAKED-EYE DETECTION; AQUEOUS-SOLUTION; RATIOMETRIC DETECTION; LIVING CELLS; CHEMODOSIMETRIC PROBE; GAS STATE; IN-VITRO; TURN-ON; SENSOR; ESIPT;

D O I：

10.1016/j.saa.2020.118075

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Hydrazine is a kind of widely used industrial raw material and a toxic biochemical reagent. Due to its toxic to organisms, hydrazine has been classified to be a hazardous environmental pollutant. It is urgent to develop fluorescent probe tools for selective sensitivity detection of hydrazine in the environment and the body. We developed here a new coumarin-based fluorescent probe for hydrazine detection. The probe can selectively detect hydrazine over other environmental and endogenous interfering analyses with a large off-on fluorescence response. The detection limit is 8.55 ppb, which is well below the allowed threshold limit value. The sensing mechanism is hydrazine-induced pyrazole ring formation, which is confirmed by HRMS and INT calculation methods. Additionally, the probe could also be applied for hydrazine imaging in living HeLa cells. (C) 2020 Published by Elsevier B.V.

引用

页数：7

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